一种稳定多基替代能量化合物,通过在1,2,3-2H-triazole/1,2,4-triazole框架中的增强结合来实现
1School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.
The Journal of organic chemistry
|December 23, 2025
概括
研究人员使用三环三醇系统开发了一种新的中性能量化合物. 这种化合物具有高密度,优异的引爆性能和低灵敏度,性能优于HMX.
科学领域:
- 能量材料科学 能量材料科学
- 有机化学 有机化学
- 材料科学 材料科学 材料科学
背景情况:
- 1,2,3-二醇框架是开发高能量密度材料 (HEDM) 的关键组成部分.
- 这些材料具有高含量和可调节的能量特性,使它们对先进应用具有吸引力.
研究的目的:
- 合成和表征一种基于三环三醇系统的新型中性能量化合物.
- 为了评估化合物的密度,引爆性能和灵敏度.
主要方法:
- 目标化合物的合成:4,5-bis(5-(trinitromethyl) -4H-1,2,4-triazol-3-yl) -2H-1,2,3-triazole.
- 化合物的结构和性质的表征.
- 测量密度,氧气平衡,爆炸速度,爆炸压力和冲击灵敏度.
主要成果:
- 合成的化合物具有两个由三环 (1,2,4-/1,2,3-/1,2,4-triazole) 系统桥接的三甲基组.
- 该分子具有高密度 (1.86 g cm−3),正氧平衡 (+7.9%) 和出色的爆炸性能 (D = 9149 m/s,P = 37.5 GPa).
- 该化合物表现出低冲击灵敏度 (10 J),超过了基准爆炸物HMX.
结论:
- 新型三环三醇化合物是一种有前途的能量材料.
- 它的高能量输出和低灵敏度的结合使其成为现有爆炸物 (如HMX) 的优质替代品.
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