一种由SiO2-ZrO2修改的新型烯酸树脂气凝,用于有效的热保护和绝缘
Yifan Zhan1, Chunhui Zhang1, Liangjun Li2
1State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China.
Gels (Basel, Switzerland)
|December 24, 2025
概括
这项研究开发了先进的--烯酸树脂气凝 (SZPA),具有增强的隔热和抗氧化性能. 这些混合气凝显示出对高温航空航天应用的显著改进.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术 纳米技术
- 航空航天工程 航空航天工程
背景情况:
- 烯酸气凝提供了潜在的热保护,防止剥离.
- 无机有机杂交网络可以提高氧化和废弃性抵抗.
研究的目的:
- 为SiO2-ZrO2-phenolic树脂气凝 (SZPA) 制定一个阶段性杂交策略.
- 为了增强用于航空航天应用的基气凝的氧化和剥离电阻.
主要方法:
- 采用了一步骤的混合化策略,涉及纳米和的物理混合.
- 构建了一个3D混合-网络,随后分散了子纳米粒子.
- 环境压力干燥被用来获得层次的纳米孔状SZPA.
主要成果:
- 在SZPA表现出降低的导热率 (0.0419-0.0431 W/(m·K)) 和增加的特定表面积 (190-232 m2/g).
- 无机网络改善了剩余质量,氧化抵抗和热稳定性.
- SZPA-4显示出优异的绝热性能,在600秒暴露于1200°C火焰后,后面表面温度为74.4°C.
结论:
- 开发的SZPA显示出卓越的绝热和稳定性,适用于高温环境.
- 这项研究提供了一种可行的方法,用于制造高性能基复合气凝.
- 这些发现扩大了这些气凝在航空航天热保护系统中的潜在应用.
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