通过增强结合来恢复能量密度,用于高性能复合材料相变材料
Jia Liu1,2, Zi-Rui Li1,2, Biao Feng1,2
1State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou, People's Republic of China.
Advanced materials (Deerfield Beach, Fla.)
|December 24, 2025
概括
研究人员通过修改纳米填充剂,增强了用于储存热能的相变材料 (PCM). 这一策略可以恢复复合PCM中的潜在热损失,改善能量密度和热导率.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 储能 储能 储能 储能 储能 储能
背景情况:
- 换相材料 (PCM) 对于热能储存至关重要.
- 在PCM中同时实现高潜热和高热导率是具有挑战性的.
- 复合PCM通常会牺牲潜在的热量,以改善导热性.
研究的目的:
- 开发一种用于复合PCM中恢复潜在热损失的策略.
- 为了提高相变材料的能量密度和导热性.
- 为了使PCM在高能量密度和功率密度下实现平衡的性能.
主要方法:
- 使用基基改性纳米填充剂来加强填充剂和矩阵PCM之间的分子连接.
- 使用纳米填充剂上的基组重建分子间键.
- 使用分子模拟来确认键的形成.
主要成果:
- 在使用氧化石墨烯的基于红醇的复合PCM中显著恢复潜热.
- 实现了复合性红醇在1%重量负载时的超高潜热 (328.5±0.9 J g-1).
- 验证了该策略对其他矩阵PCM,如酸和水合盐的适用性.
结论:
- 拟议的战略有效地恢复了复合PCM中的能量密度损失.
- 纳米填充剂的基修饰增强了分子间相互作用,增加了潜热.
- 这种方法有助于开发具有平衡性能的基于聚醇的复合PCM.
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