作为超深钻石内含物的潜在来源,缩CaCO3-Fe-SiO2中的氧化还原反应是超深钻石内含物的潜在来源
Mengqi Guo1, Xinyang Li2, Zhu Mao3,4,5
1Synergetic Extreme Condition High-Pressure Science Center, State Key Laboratory of High Pressure and Superhard Materials, College of Physics, Jilin University, Changchun, China.
Scientific reports
|December 25, 2025
概括
碳酸 (CaCO3) 被潜入深层地幔,经历氧化还原反应. 形成特定的矿物质组合,可能表明在700-1300公里的深度形成钻石.
科学领域:
- 地质化学 地质化学
- 矿物物理 矿物物理
- 地球深层的过程.
背景情况:
- 碳酸 (CaCO3) 在地球表面是丰富的,并通过潜水运输到地幔.
- 了解深层地幔的碳循环需要研究CaCO3在极端条件下的行为.
研究的目的:
- 使用CaCO3-Fe-SiO2系统模拟海底地的深层地幔环境.
- 为了研究高压和高温下CaCO3的相变和反应.
主要方法:
- 在现场进行了X射线衍射实验,使用激光加热的钻石天细胞.
- 实验涵盖了25-53 GPa的压力和1200-2250 K.的温度.
主要成果:
- 在1500-2000K之间发生了氧化还原反应,形成了CaSiO3 + FeO + Fe3C.
- 在更高的温度下 (2000-2250K),产生了CaSiO3 + Fe3O4 + Fe7C3.
- Fe3O4 和 Fe7C3 组合被确定为超深钻石中潜在的包含物.
结论:
- 形成CaSiO3,FeO,Fe3C,Fe3O4和Fe7C3为深层地幔地质化学提供了洞察力.
- 矿物质组合Fe3O4 + Fe7C3可能表明在700-1300公里的深度形成了钻石.
- 这项研究有助于了解深层地幔的碳循环和超深层钻石的起源.
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