硫酸盐攻击和重金属属性的演变 烧结 改性焚烧 灰 飞 砂
Xiaodong Ma1, Jialong Guo1, Xianjun Li1
1School of Electric Power, Civil Engineering and Architecture, Shanxi University, Taiyuan 030031, China.
Langmuir : the ACS journal of surfaces and colloids
|December 26, 2025
概括
在水泥中的焚烧飞灰显示出各种各样的硫酸盐抗性. 化飞灰 (C-IFA) 砂表现不佳,而未化 (U-IFA) 和直接化 (D-IFA) 则表现出更好的重金属固定性和硫酸盐耐受性.
科学领域:
- 材料科学 材料科学 材料科学
- 环境科学 环境科学
- 土木工程 土木工程是指土木工程.
背景情况:
- 焚烧飞灰 (IFA) 是一种危险废物,在经过热处理后经常被用于水泥中.
- 含有IFA的水泥中重金属的长期环境安全性需要进一步调查.
- 硫酸盐的攻击对水泥的耐用性和重金属的固定性构成了重大挑战.
研究的目的:
- 为了评估重金属安全性和混凝土的砂性能,在硫酸盐攻击下使用不同修改的焚烧飞灰.
- 为了比较未化IFA (U-IFA),直接化IFA (D-IFA) 和化IFA (C-IFA) 改性水泥砂的硫酸盐耐受性和重金属漏行为.
- 评估在水泥材料中使用经过处理的飞灰对环境安全的长期影响.
主要方法:
- 包含U-IFA,D-IFA和C-IFA的砂样本受到循环硫酸盐攻击.
- 测量了砂质量变化,压力强度和表面重金属度.
- 在弱酸性条件下进行了重金属漏试验,并分析了Pb和Cr的不稳定分数.
主要成果:
- 砂质量最初增加,然后在硫酸盐攻击期间减少;U-IFA显示了最大的质量增加.
- C-IFA砂表现出最早的裂变和压力强度显著降低 (>22%).
- 在酸性条件下,重金属的漏增加,特别是D-IFA和C-IFA,但仍在可接受的范围内;不稳定的Pb和Cr分量增加,但整体风险低至中.
结论:
- C-IFA 砂的硫酸盐耐受性明显低于 U-IFA 和 D-IFA 砂.
- 硫酸盐攻击加速了迫击炮的恶化,并影响了重金属的固定.
- 在复杂的服务条件下加强对含有危险废物的水泥的长期环境安全评估至关重要.
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