化弱协调溶剂使高实际容量低温电池成为可能
Ningxin Wang1, Menglu Li2, Haiqing Lv2
1State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Key Laboratory of Physics and Technology for Advanced Batteries, Ministry of Education, Jilin University, Changchun 130012, P. R. China.
ACS applied materials & interfaces
|December 27, 2025
概括
这项研究引入了三酸 (PFPN) 来增强用于寒冷气候的离子电池. 修改后的电解质提高了低温性能和稳定性,使高能量密度成为可能.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 离子电池需要高面积容量和稳定的低温运行才能实际使用.
- 低温下缓慢的动力学和界面不稳定性阻碍了电池的发展.
研究的目的:
- 为了提高离子电池在低温下的性能.
- 为了提高骑行过程中的界面稳定性.
主要方法:
- 在NaPF6-PC/DEC电解质中将乙氧三酸 (PFPN) 纳入.
- 研究PFPN对Na+迁移动力学和离子再分配的影响.
- 在-40°C下对NaNi1/3Fe1/3Mn1/3O2硬碳电池进行电化学测试.
主要成果:
- PFPN削弱了溶剂离子相互作用,在低温下增强了Na+迁移.
- PFPN有助于稳定的阴离子衍生的间相形成.
- 电池实现了2.0 mAh cm-2面积容量和89.9%的保留200个周期在-40°C.
- 袋式电池提供了112.5Wh/kg-1的能量密度.
结论:
- 修改PFPN的电解质显著提高了低温离子电池的性能.
- 这种方法对开发用于寒冷地区的高面积容量电池具有前景.
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