无可逆转的铁电到抗铁电相变的扩散动态过程和速率极限
Mingyue Ge1,2, Bing Han3, Zhengwei Xiong2
1Institute of Fluid Physics, China Academy of Engineering Physics, Mianyang, China.
Nature communications
|December 30, 2025
概括
这项研究揭示了硫酸中铁电到抗铁电相变的过程是一个缓慢的,放松的过程,而不是一个快速的原子重新排列. 这一发现影响了储能和信息技术的材料设计.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
背景情况:
- 铁电到反铁电相转换在矿中是储能和信息技术的关键.
- 之前的研究将这些转变描述为快速的,由原子重排驱动的第一阶过程.
研究的目的:
- 研究铁电到抗铁电相变的动态过程.
- 为了纠正人们对过渡动力学的普遍理解.
- 为材料设计和设备可靠性提供理论框架.
主要方法:
- 通过中子衍射观察相变.
- 在现场可变温度传输电子显微镜用于动态分析.
- 密度函数理论模拟用于机械洞察力.
- 用于过渡动态的多尺度相场建模.
主要成果:
- 在低温下观察到Pb(Zr0.97Ti0.03) O3中不可逆转的铁电到抗铁电相变.
- 传输电子显微镜揭示了一个缓慢的,扩散的,放松的动态过程,挑战了先前的假设.
- 密度函数理论表明,温度依赖的能量障碍会导致不可逆转的过渡行为.
结论:
- 在Pb(Zr0.97Ti0.03) O3中,铁电到抗铁电相变是一个缓慢的,放松的过程.
- 这项工作建立了一个多尺度模型来理解过渡动态.
- 这些发现为优化用于储能和信息设备的材料提供了基础.
相关概念视频
Ferromagnetism
2.9K
Materials like iron, nickel, and cobalt consist of magnetic domains, within which the magnetic dipoles are arranged parallel to each other. The magnetic dipoles are rigidly aligned in the same direction within a domain by quantum mechanical coupling among the atoms. This coupling is so strong that even thermal agitation at room temperature cannot break it. The result is that each domain has a net dipole moment. However, some materials have weaker coupling, and are ferromagnetic at lower...
2.9K
Phase Transitions: Melting and Freezing
14.5K
Heating a crystalline solid increases the average energy of its atoms, molecules, or ions, and the solid gets hotter. At some point, the added energy becomes large enough to partially overcome the forces holding the molecules or ions of the solid in their fixed positions, and the solid begins the process of transitioning to the liquid state or melting. At this point, the temperature of the solid stops rising, despite the continual input of heat, and it remains constant until all of the solid is...
14.5K
Reversible and Irreversible Processes
5.5K
The thermodynamic processes can be classified into reversible and irreversible processes. The processes that can be restored to their initial state are called reversible processes. It is only possible if the process is in quasi-static equilibrium, i.e., it takes place in infinitesimally small steps, and the system remains at equilibrium However, these are ideal processes and do not occur naturally. An ideal system undergoing a reversible process is always in thermodynamic equilibrium within...
5.5K
Phase Transitions
22.2K
Whether solid, liquid, or gas, a substance's state depends on the order and arrangement of its particles (atoms, molecules, or ions). Particles in the solid pack closely together, generally in a pattern. The particles vibrate about their fixed positions but do not move or squeeze past their neighbors. In liquids, although the particles are closely spaced, they are randomly arranged. The position of the particles are not fixed—that is, they are free to move past their neighbors to...
22.2K
Theory of Metallic Conduction
1.7K
The conduction of free electrons inside a conductor is best described by quantum mechanics. However, a classical model makes predictions close to the results of quantum mechanics. It is called the theory of metallic conduction.
In this theory, Newton's second law of motion is used to determine the acceleration of an electron in the presence of an applied electric field. Then, its velocity is expressed via this acceleration.
An electron moves through the crystal, containing positive ions,...
In this theory, Newton's second law of motion is used to determine the acceleration of an electron in the presence of an applied electric field. Then, its velocity is expressed via this acceleration.
An electron moves through the crystal, containing positive ions,...
1.7K
Fermi Level Dynamics
622
The vacuum level denotes the energy threshold required for an electron to escape from a material surface. It is usually positioned above the conduction band of a semiconductor and acts as a benchmark for comparing electron energies within various materials.
Electron affinity in semiconductors refers to the energy gap between the minimum of its conduction band and the vacuum level and it is a critical parameter in determining how easily a semiconductor can accept additional electrons.
The work...
Electron affinity in semiconductors refers to the energy gap between the minimum of its conduction band and the vacuum level and it is a critical parameter in determining how easily a semiconductor can accept additional electrons.
The work...
622


