用重金属污染回收聚合物的水泥复合材料的评估:朝着可持续利用的方向
Tilen Turk1, Petra Štukovnik1, Marjan Marinšek2
1Faculty of Civil and Geodetic Engineering, University of Ljubljana, Jamova 2, 1000 Ljubljana, Slovenia.
Materials (Basel, Switzerland)
|December 31, 2025
概括
来自矿山尾矿的回收聚合物由于重金属而延迟了水泥置,但最多可安全使用25%. 由于可能释放硫酸盐,长期耐用性需要进一步研究.
科学领域:
- 材料科学 材料科学 材料科学
- 土木工程 土木工程是指土木工程.
- 环境科学 环境科学
背景情况:
- 回收聚合物为环境提供了好处,但可能会影响水泥的水化,特别是当从富含重金属的采矿副产品中采购时.
- 了解这些化学相互作用对于可持续的建筑实践至关重要.
研究的目的:
- 研究Pb-Zn矿山尾矿回收聚合物的对水泥水化和早期老化性能的影响.
- 确定导致水化延迟和机械性能降低的特定机制.
主要方法:
- 回收聚合物的特性 (XRD).
- 监测水泥水化 (超声波脉冲速度,温度演变).
- 评估机械性能和相位演变 (SEM-EDS,热力学建模).
主要成果:
- 在回收聚合物中,重金属含量阶段延迟了水泥定时间长达28小时.
- 早期的力量减少了,但在第7天恢复到25%的替换.
- 持续的硫酸盐阶段表明潜在的长期耐用性风险.
结论:
- 来自矿山尾矿Pb-Zn的回收聚合物可添加高达25体积%的聚合物,同时保持可接受的性能.
- 化延迟与金属酸盐复合物的形成有关.
- 需要进一步的研究来解决硫酸盐引起的长期耐用性问题.
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