二氧化碳注射度对甲扩散系数的影响
Jianchi Hao1, Shuangming Wang1, Hu Wen2
1College of Geology and Environment, Xi'an University of Science and Technology, Xi'an 710054, Shaanxi, China.
ACS omega
|January 1, 2026
概括
在煤层中注入二氧化碳 (CO2) 取代甲 (CH4) 需要复杂的气体相互作用. 这项研究模拟了扩散,揭示了CH4扩散随着CO2注入而增加,而CO2扩散则减少.
科学领域:
- 地质科学 地质科学
- 化学工程是化学工程的重要组成部分.
- 能源科学 能源科学
背景情况:
- 煤层储存了大量的甲 (CH4),这是一个强大的温室气体.
- 二氧化碳 (CO2) 注入是提高煤床甲 (CBM) 回收和碳封存的关键策略.
- 了解气体扩散动态对于优化CBM生产和CO2注入效率至关重要.
研究的目的:
- 研究CH4和CO2在煤层中CO2-CH4排放过程中的吸附,脱附和扩散行为.
- 开发CH4和CO2的扩散系数的计算模型.
- 分析二氧化碳注入度对气体扩散的影响.
主要方法:
- 在模拟CBM条件下对煤炭中的气体吸附,脱附和扩散进行实验性调查.
- 基于随时间推移气体扩散量实验数据的扩散模型的开发.
- 对气体扩散系数与实验时间和二氧化碳注入度相关的分析.
主要成果:
- 在CH4排放过程中,二氧化碳的注入过程分为三个不同的阶段:同时替换/排放,主导替换和稳定状态.
- 随着实验时间的增加,CH4和CO2的扩散系数迅速下降.
- 增加二氧化碳注入度可以增强CH4扩散,同时抑制二氧化碳扩散.
结论:
- 扩散在连接吸附,脱附和透方面发挥着关键作用,显著影响CBM生产和CO2注入.
- 已建立的扩散模型为煤层中的气体运输机制提供了宝贵的见解.
- 优化二氧化碳注入策略需要仔细考虑其对CH4和二氧化碳扩散动态的影响.
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