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低温热处理提高了O2型丰富的基材料的结构稳定性

Yufang Chen1, Xiao Zhang1, Peitao Xiao1

  • 1Department of Materials Science and Engineering, College of Aerospace Science and Engineering, National University of Defense Technology, Changsha, Hunan 410000, China. chenyufang@nudt.edu.cn.

Chemical communications (Cambridge, England)
|January 2, 2026
PubMed
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No abstract available in PubMed .

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Activated manganese(IV) oxide can selectively oxidize allylic and benzylic alcohols via a radical intermediate mechanism. Primary allylic alcohols are oxidized to aldehydes, while secondary allylic alcohols yield ketones. The redox reaction of potassium permanganate with an Mn(II) salt such as manganese sulfate (under either alkaline or acidic conditions), followed by thorough drying, yields the oxidizing agent: activated MnO2. While MnO2 is insoluble in the solvents used for the reaction, the...
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