磁性纳米催化剂的最新进展,用于合成 imidazo[1,2-a]pyridine框架

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Synthesis and Characterization of Functionalized Metal-organic Frameworks
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Published on: September 5, 2014

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Mohamed Abu Shuheil1, G Padma Priya2, Amaal Mohammed Ali3

  • 1Faculty of Allied Medical Sciences, Hourani Center for Applied Scientific Research, Al-Ahliyya Amman University Amman Jordan m.abushuhel@ammanu.edu.jo.

RSC advances
|January 5, 2026
PubMed
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No abstract available in PubMed .

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Preparation of 1° Amines: Azide Synthesis01:22

Preparation of 1° Amines: Azide Synthesis

Direct alkylation of ammonia produces polyalkylated amines, along with a quaternary ammonium salt. To exclusively prepare primary amines, the azide synthesis method can be used.
Azide ions act as good nucleophiles and react with unhindered alkyl halides to form alkyl azides. Alkyl azides do not participate in further nucleophilic substitution reactions, thereby eliminating the chances of polyalkylated products. Alkyl azides are reduced by hydride-based reducing agents, like lithium aluminum...