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设计非对称的D-π-A BODIPY作为光动力疗法的高性能光敏剂

Ziyu Zhai1, Fangjian Cai1, Pengfei Li1

  • 1State Key Laboratory of Coordination Chemistry, Collaborative Innovation Center of Advanced Microstructures, School of Chemistry and Chemical Engineering Nanjing University, 210023 Nanjing, China. zshen@nju.edu.cn.

Chemical communications (Cambridge, England)
|January 5, 2026
PubMed
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No abstract available in PubMed .

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Photochemical Electrocyclic Reactions: Stereochemistry01:26

Photochemical Electrocyclic Reactions: Stereochemistry

The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
Selection Rules: Photochemical Activation
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