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Updated: Jan 13, 2026

Monitoring the Reductive and Oxidative Half-Reactions of a Flavin-Dependent Monooxygenase using Stopped-Flow Spectrophotometry
12:08

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Published on: March 18, 2012

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通过NRVS和DFT揭示的黄铁NO还原酶的氧桥活性位点

Filipe Folgosa1, Vladimir Pelmenschikov2, Giorgio Caserta2

  • 1Instituto de Tecnologia Química e Biológica António Xavier, Universidade Nova de Lisboa, Oeiras 2780-157, Portugal.

Proceedings of the National Academy of Sciences of the United States of America
|January 6, 2026
PubMed
概括

黄铁蛋白 (FDPs) 使用二铁活性位点来排毒反应性中间体. 我们使用57Fe NRVS揭示了FDP活性部位的氧化还原相关结构变化,澄清了其协调环境和反应性.

关键词:
在 DFT 方面,它是最重要的.没有减少,没有减少.在NRVS中使用NRVS.铁酸二氧化酶 铁酸二氧化酶反应机制的反应机制.

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