关于稀土元素的电子阴性,基于相对价值电子结合能量
1Solid State Chemistry, Institut für Physik, Universität Augsburg, Augsburg D-86159, Germany.
Inorganic chemistry
|January 7, 2026
概括
使用相对价值电子结合能 (ReVEBE) 提出了新的稀土元素电子负性. 这些值与现有的负电子度量表保持一致,为这些元素提供了一种新的方法.
科学领域:
- 无机化学 无机化学
- 量子化学 是一个量子化学.
- 频谱学是一种光谱学.
背景情况:
- 电子阴性是一种基本的化学性质,但稀土元素的值较少确立.
- 现有的确定电子负性的方法可能无法完全捕捉稀土元素的细微差别.
研究的目的:
- 提出一种新的方法来确定稀土元素的电子阴性.
- 使用实验光谱数据来确定这一点.
主要方法:
- 从NIST原子光谱数据库计算平均相对价值电子结合能量 (ReVEBE).
- 修改基本状态平均价值电子结合能量的概念.
主要成果:
- 建议从ReVEBE.提取的稀土元素的电子阴性值.
- 获得的值与已建立的尺度 (艾伦,保林,穆利肯) 强烈一致.
- 同时还观察到与类的光学电子负性相关性.
结论:
- ReVEBE方法提供了一种可靠的方法,用于稀土元素的电子阴性.
- 这种方法提供了一种一致的方式来理解周期表中的结合和反应性.
- 不同物理原理之间的协议突显了研究结果的稳定性.
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