在非局部弹性网络中相位分离的动态
Oliver W Paulin1, Yicheng Qiang1, David Zwicker1
1Max Planck Institute for Dynamics and Self-Organization, Am Faßberg 17, 37077 Göttingen, Germany. david.zwicker@ds.mpg.de.
Soft matter
|January 7, 2026
概括
聚合物凝的非局部弹性防止在相位分离过程中粗,形成有图案的域. 这种动态理论将相位分离与大变形波电弹性联系起来,用于实验性比较.
科学领域:
- 软物质物理学 软物质物理学
- 材料科学 材料科学 材料科学
- 生物物理学的生物物理.
背景情况:
- 弹性网络中的相分离对于生物和工业系统至关重要,如生物分子凝结物和软沉积物.
- 以前的理论表明,当域大小与网络孔径大小相匹配时,平衡和非局部弹性效应驱动模式形成.
- 在合成聚合物凝中的实验证据表明,在特定条件下,出现有模式的相.
研究的目的:
- 开发一个动态理论合阶段分离与非局部弹性,使用大变形弹性.
- 为了研究相隔的参数空间和不同弹性模型的影响.
- 为理论模型和实验结果之间的定量比较提供一个框架.
主要方法:
- 开发了一种基于大变形波流弹性的动态理论.
- 采用线性稳定性分析来确定相隔条件.
- 利用数值模拟来研究弹性模型和参数变化的影响.
主要成果:
- 局部弹性可以阻碍相位分离和改变域数,但不能防止粗化.
- 非局部弹性有效地阻止了粗,从而形成具有定义长度尺度的图案域.
- 模式域的特征长度尺度与网络度相反相关.
结论:
- 非局部弹性是形成弹性网络内的液体混合物中稳定,有模式的相的关键.
- 开发的动态理论准确地模拟了模式的形成,并提供了对粗化停止的见解.
- 该框架有助于与实验数据进行直接比较,特别是对于应变强化网络.
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