原子工程 RuW@IrRuW纳米催化剂用于高级性氧化反应
Lianming Zhao1, Shouao Li1, Chang Xu1
1Shandong Key Laboratory of Intelligent Energy Materials, School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao, Shandong 266580, China.
在N-doped空心碳纳米圈上设计了一种新的RuW@IrRuW纳米催化剂,用于在离子交换膜燃料电池 (AEMFC) 中增强氧化反应 (HOR),实现卓越的活性和稳定性.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 纳米技术纳米技术
背景情况:
- 阳离子交换膜燃料电池 (AEMFC) 被缓慢的动力学和氧化反应 (HOR) 的不稳定性所阻碍.
- 开发高效,稳定和耐CO电催化剂对于推进AEMFC技术至关重要.
研究的目的:
- 为氧化反应 (HOR) 设计一种高度活性和稳定的纳米催化剂.
- 研究AEMFCs中新型催化剂的结构-活性-稳定性关系.
主要方法:
- 湿化学浸和原子替代合成RuW@IrRuW纳米催化剂在N-doped空心碳纳米圈 (NHCSs) 上.
- 在0.1M KOH中进行电化学表征,以评估HOR活性,稳定性和CO耐受性.
- 结合实验和理论研究 (DFT) 以阐明反应机制.
主要成果:
- RuW@IrRuW/NHCSs催化剂实现了3257.57 mA mg−1的质量活性和2.85 mA cm−2的特异活性,显著超过商业Pt/C.
- 经过4万秒的微不足道衰变,表现出出色的稳定性和优越的CO耐受性 (在CO中2900秒后具有85.9%的活性).
- 原子分层的IrRuW外和NHCS支持有助于双重活性站点,优化电子结构和增强的金属载体相互作用.
结论:
- 设计的RuW@IrRuW/NHCSs催化剂提供了一种可行的策略,以克服HOR电催化中的活动稳定性权衡.
- 这项工作为高效,耐用和耐碳的AEMFC铺平了道路.
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