一个相场模型:接触角度歇斯底里是由多稳定的表面组成驱动的
Hongmin Zhang1, Shan Lyu2, Martin Reder3
1Institute of Nanotechnology, Karlsruhe Institute of Technology, Hermann-von-Helmholtz Pl. 1, 76344, Eggenstein-Leopoldshafen, Germany.
Journal of colloid and interface science
|January 8, 2026
概括
这项研究引入了流体-固体相互作用的新模型,用分子级表面能量解释了接触角度歇斯底里和棒滑行为. 它强调了表面组成和扩散在流体动力学中的作用.
科学领域:
- 物理 物理学 物理
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 实验数据显示,在疏水基板附近的液体-固体接口上,密度减少.
- 这表明了异质和扩散的流体-固体界限.
- 流体-固体界面的表面构成可能存在多个稳定的状态.
研究的目的:
- 开发一个能够解释多稳定的表面构成的模型.
- 在光滑的基板上模拟静态和动态接触角度歇斯底里 (CAH).
- 在分子水平上调查CAH和棒滑行为起源.
主要方法:
- 引入了一个非单调的墙壁自由能量配方.
- 将其集成到一个热力学一致的相场模型中.
- 允许通过分子扩散来实现接触线运动的墙壁自由能量放松.
主要成果:
- 成功复制了多稳定的表面组成和静态CAH.
- 在滴滴运动期间捕获的动态CAH,包括接触线固定和前进/后退状态.
- 在CAH的滴滴滑动过程中观察到出现的粘滑行为.
结论:
- CAH和粘滑行为只能从分子级流体-固体相互作用中产生.
- 表面构成和界面扩散是关键因素,在经典模型中经常错过.
- 该框架弥合了热力学和水力学观点,提供了对界面上的滑动和摩擦的洞察力,这与微流体学有关.
更多相关视频
06:26Orientational Transition in a Liquid Crystal Triggered by the Thermodynamic Growth of Interfacial Wetting Sheets
Published on: May 15, 2017
7.5K
11:38Combining Microfluidics and Microrheology to Determine Rheological Properties of Soft Matter during Repeated Phase Transitions
Published on: April 19, 2018
8.4K
相关概念视频
Contact Angle
18.0K
When a solid is dipped inside a liquid, the liquid surface becomes curved near the contact. For some solid–liquid interfaces, the liquid is pulled up along the solid, while for others, the liquid surface is convex or depressed near the solid surface. This phenomenon can be explained using the concept of cohesive and adhesive forces.
The adhesive force is the molecular force between molecules of different materials, that is, between the molecules of the solid and the liquid. The cohesive...
The adhesive force is the molecular force between molecules of different materials, that is, between the molecules of the solid and the liquid. The cohesive...
18.0K
Magnetostatic Boundary Conditions
1.6K
An electric field suffers a discontinuity at a surface charge. Similarly, a magnetic field is discontinuous at a surface current. The perpendicular component of a magnetic field is continuous across the interface of two magnetic mediums. In contrast, its parallel component, perpendicular to the current, is discontinuous by the amount equal to the product of the vacuum permeability and the surface current. Like the scalar potential in electrostatics, the vector potential is also continuous...
1.6K
Phase Transitions: Sublimation and Deposition
19.6K
Some solids can transition directly into the gaseous state, bypassing the liquid state, via a process known as sublimation. At room temperature and standard pressure, a piece of dry ice (solid CO2) sublimes, appearing to gradually disappear without ever forming any liquid. Snow and ice sublimate at temperatures below the melting point of water, a slow process that may be accelerated by winds and the reduced atmospheric pressures at high altitudes. When solid iodine is warmed, the solid sublimes...
19.6K
