动态同质催化能实现稳定和高效的水性有机氧化还原流电池
Qiliang Chen1, Yajie Jin1, Siyuan Ren1
1College of Chemistry, Zhengzhou University, Zhengzhou 450001, P. R. China.
Journal of the American Chemical Society
|January 9, 2026
概括
这项研究引入了一种新型的有机硫氧化还原流电池 (OSRFB),采用负担得起的RSSR解质. 动态催化使电网储能具有高能量密度和超长周期寿命.
科学领域:
- 电化学
- 材料科学
- 能量储存
背景情况:
- 有机分子是用于氧化还原流电池 (RFB) 的,但在能量密度和稳定性方面面临挑战.
- 开发稳定,负担得起的分子对于电网规模的储能至关重要.
研究的目的:
- 为长寿命RFB开发稳定且负担得起的有机活性分子.
- 提高RFB中的有机硫化合物的动力学和性能.
主要方法:
- 使用低成本,工业规模的RSSR (硫二硫化物) 作为溶解物.
- 应用动态同质催化使用元素加速氧化还原动力学.
- 研究了电化学激活能量障碍和电池性能指标.
主要成果:
- 将RSSR的电化学激活能量屏障降低了三分之一以上 (从38.8到<25 kcal mol-1).
- 实现了高能量密度 (53Wh L-1 ),高能量效率 (74.5%) 和异常高的库伦比效率 (>99.97%).
- 经证明的超长周期寿命为134. 7天 (0. 25M RSSR) 和113. 9天 (1. 1M RSSR),容量衰减最小.
结论:
- 开发的水性有机硫RFB (OSRFB) 显示了超长时间储能的巨大潜力.
- 动态催化有效地提高了有机硫溶解物的性能.
- 该系统为电网储能应用提供了有希望的,具有成本效益的解决方案.
更多相关视频
09:22Synthesis and Performance Evaluations of ZnCoS/ZnCdS with Twin Crystal Structure for Multifunctional Redox Photocatalysis in Energy Applications
Published on: July 25, 2025
660
10:15Solar-Driven Electrochemical Green Fuel Production from CO2 and Water Using Ti3C2Tx MXene-Supported CuZn and NiCo Catalysts
Published on: November 7, 2025
443
相关概念视频
Batteries and Fuel Cells
30.7K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
30.7K
Voltaic/Galvanic Cells
63.0K
Spontaneous Chemical Reactions
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
63.0K
Electrolysis
30.1K
In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
30.1K
Redox Equilibria: Overview
1.5K
A reduction-oxidation reaction is commonly called a redox reaction. In a redox reaction, electrons are transferred from one species to another rather than being shared between or among atoms. The reducing agent or reductant is the species that loses electrons and gets oxidized in the process. The species that gains electrons and gets reduced in the process is the oxidizing agent or oxidant. Redox reactions are represented as two separate equations called half-reactions, where one equation...
1.5K
Redox Reactions
58.2K
Oxidation-reduction or redox reactions involve the transfer of electrons from one molecule or atom to another. When an atom gains an electron, another atom must lose an electron, meaning oxidation and reduction must occur together. Since the redox occurs in pairs, the atom that gets oxidized is also called the reducing agent or reductant, and the atom that is reduced is also called the oxidizing agent or oxidant. A straightforward way to remember the definitions of oxidation and reduction is...
58.2K
Redox Reactions
876
Redox reactions are vital biochemical processes that underpin energy metabolism in cells. These reactions involve the transfer of electrons between molecules, occurring in tandem as oxidation and reduction. Oxidation refers to the loss of electrons, while reduction denotes their gain. This coupling ensures the seamless flow of electrons through metabolic pathways. For example, in bacterial metabolism, glucose undergoes oxidation to carbon dioxide, while oxygen is simultaneously reduced to...
876
