绿色纤维增强层材:无烯UPe与VTES功能化的ZrO2和亚麻织物
Slavko Mijatov1, Milica Rančić2, Tihomir Kovačević1
1Military Technical Institute, Ratka Resanovića 1, 11030 Belgrade, Serbia.
Polymers
|January 10, 2026
概括
这项研究引入了无烯不和聚 (UPe) 纳米复合材料,用功能化子纳米颗粒 (ZrO2-VS) 增强. 这些可持续的复合材料显示了增强的机械性能,为先进材料提供了低危险的替代品.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 纳米技术纳米技术
背景情况:
- 对于可持续复合材料的需求不断增长,作为合成材料的替代品.
- 需要先进的聚合物矩阵,以提高机械性能和减少对环境的影响.
- 探索自然纤维和纳米粒子增强,以提高复合材料的性能.
研究的目的:
- 开发和评估无烯不和聚 (UPe) 纳米复合材料,增强用乙烯基-三氧- (VTES) 功能化子纳米颗粒 (ZrO2-VS).
- 研究ZrO2-VS对基于UPE的复合材料和亚麻织物层层的分散,界面粘附和机械性能的影响.
- 为了比较ZrO2-VS增强复合材料的性能与未经修改的ZrO2和整洁的UPe的复合材料.
主要方法:
- 使用VTES合成和功能化基纳米颗粒.
- 纳米颗粒在无烯UPe矩阵中的分散,使用高剪切混合.
- 使用富里埃变换红外光谱法 (FTIR) 进行特征化,用于治疗转换.
- 通过扫描电子显微镜与能量分散式X射线光谱学 (SEM/EDS) 来评估微观结构和元素组成.
- 通过拉力测试和动态机械分析 (DMA) 评估机械性能.
主要成果:
- 与未经修改的ZrO2.2相比,ZrO2纳米粒子 (ZrO2-VS) 的VTES功能化显著改善了UPE矩阵内的分散和界面粘附.
- ZrO2-VS/UPe纳米复合材料的抗拉强度和储存模量高于未经修改的ZrO2/UPe.
- 用ZrO2-VS/UPe增强的亚麻布层层实现了72.2 ± 3.6 MPa的抗拉强度,优于整洁的UPe和未经修改的ZrO2/UPe控制器.
- DMA揭示了在各种温度范围内储存模块的实质性增加,对玻璃过渡温度 (Tg) 的影响最小.
结论:
- 通过西兰介导的纳米粒子-矩阵-纤维桥接增强了天然纤维复合材料的机械性能.
- 使用ZrO2-VS功能化的无烯UPe纳米复合材料提供了一个有希望的低烯危险途径,以改善材料性能.
- 这些发现支持使用天然纤维和功能化纳米粒子开发可持续和高性能复合材料.
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