用不同的溶剂进行水热处理,以在亚临界和超临界条件下进行复合材料回收和回收利用
José M Vázquez-Fernández1, Belén García-Jarana1, Milagrosa Ramírez-Del Solar2
1Department of Chemical Engineering and Food Technology, Faculty of Sciences, University of Cádiz, International Excellence Agrifood Campus (CeiA3), Puerto Real, 11510 Cádiz, Spain.
Polymers
|January 10, 2026
概括
使用热水处理回收碳纤维复合材料有效地分解聚合物基质,回收有价值的长碳纤维 (CFs),保留机械性能. 这种方法为航空工业废物提供了一个可持续的解决方案.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 环境科学 环境科学
背景情况:
- 航空航天领域对碳纤维 (CF) 复合材料的需求增加与大量的生产废物 (30-50%) 相反.
- 需要有效的回收方法来降低成本和环境影响.
- 传统方法难以从复合废物中回收有价值的长CF.
研究的目的:
- 调查水热处理对回收碳纤维增强复合材料的潜力.
- 评估不同溶剂和催化剂 (ZnCl2) 在分解聚合物矩阵中的有效性.
- 评估回收碳纤维的质量和性能.
主要方法:
- 碳纤维增强复合材料的水热处理,使用水,异醇,水/异醇或水/乙混合物.
- 使用和不使用化 (ZnCl2) 作为催化剂进行测试.
- 改变温度,压力和溶剂成分以优化树脂降解.
主要成果:
- 在最佳条件下达到高达92%的树脂降解 (415°C,233巴,120分钟,5重%IPA,0.1M ZnCl2).
- 回收的碳纤维保留了它们的形态和机械性能.
- 水-异醇混合物导致反应堆比单独的水更清洁;ZnCl2导致腐蚀.
结论:
- 热水处理是回收航空航天碳纤维复合材料的有希望,高效和选择性的方法.
- 该工艺允许回收高质量的碳纤维,适合重复使用.
- 水-异醇溶剂系统在可扩展性和减少维护方面具有优势.
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