通过绿色方法合成的添加LaFeO3纳米矿中的结构和物理性质相关性
Abdalrahman M Rayan1, Mehawed M Ahmed2, H A A Saadallah3
1Physics Department, Faculty of Science, Sohag University, Sohag, 82524, Egypt. muhmedabdalrahman912@gmail.com.
Scientific reports
|January 11, 2026
概括
使用Moringa oleifera提取物绿色合成配合兰铁酸盐 (LaFeO3) 纳米颗粒可增强介电和磁性质. 这为储能,传感和自旋电子设备提供了潜力.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术 纳米技术
- 固态化学 固态化学
背景情况:
- 兰铁酸盐 (LaFeO3) 是一种具有有趣磁性和介电性质的矿氧化物.
- 将LaFeO3与其他元素合,可以调整其特性以适应特定应用.
- 绿色合成方法为传统的化学途径提供了环保的替代方案.
研究的目的:
- 使用绿色路径合成Mg-doped LaFeO3纳米颗粒.
- 研究Mg2+替代对LaFeO3.3的结构,介电和磁性质的影响.
- 探索这些改性纳米颗粒的潜在应用.
主要方法:
- 使用Moringa oleifera叶片提取物进行绿色合成.
- 用X射线衍射 (XRD) 和瑞特维尔德精细化进行结构分析.
- 介电测量 介电测量 介电测量
- 振动样本磁力测量 (VSM) 和电子自旋共振 (ESR) 用于磁性表征.
主要成果:
- 成功合成了La1−xMgxFeO3纳米粒子.
- 在较高的Mg兴奋剂水平 (x ≥0.17) 观察到从立方对称到正方对称的相位过渡.
- 胺兴奋剂影响了晶格参数,增强了介电性质 (介电常数) 并抑制了介电损失.
- 随着含量增加,铁磁性行为显著改善,在x = 0.17时达到峰值.
- 兴奋剂,结构变化,氧气空缺和磁相互作用之间的相关性.
结论:
- 用Mg合的LaFeO3纳米粒子具有可调节的结构,介电和磁性.
- 绿色合成方法是有效的,对环境有利.
- 这些纳米颗粒显示出能储能,传感器和螺旋电子应用的前景.
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