以薄荷为基础的疏水性欧性溶剂作为生物基烯酸聚合物的绿色可塑剂
Janire Aramberri1, Matías L Picchio2,3, Aitor Barquero1
1POLYMAT and Department of Applied Chemistry, University of the Basque Country UPV/EHU, Joxe Mari Korta Center, Tolosa Hiribidea, 72, 20018 Donostia, Spain.
概括
基于薄荷醇的疏水性浸泡溶剂 (HESs) 为生物基烯酸薄膜中的常规增塑剂提供了一个可持续的替代品. 这些绿色塑化剂可提高材料性能,用于诸如治疗贴片等应用.
科学领域:
- 聚合物科学 聚合物科学
- 绿色化学 绿色化学
- 材料科学 材料科学 材料科学
背景情况:
- 在烯酸聚合物中的常规塑化剂由于挥发性有机化合物 (VOCs) 引起了环境和健康方面的担忧.
- 聚合物行业正在寻求可持续的替代油基单体和有毒添加剂.
研究的目的:
- 研究以薄荷醇为基础的疏水性水溶剂 (HESs) 作为生物基烯酸聚合物的环保可塑剂.
- 评估这些生物基膜的性能,特别是用于治疗性贴片应用.
主要方法:
- 通过微乳液聚合,使用生物基异甲酸盐 (IBOMA) 和2 - 奥克甲酸盐 (2-OMA) 合成烯酸薄膜.
- 添加基于薄荷醇的HES作为增塑剂.
- 薄膜特性 (化学,热,粘合剂,机械) 的全面表征.
主要成果:
- 基于薄荷醇的HES证明了生物基烯酸薄膜的有效塑化.
- 塑化剂的有效性可以通过控制键捐赠者的极性和eutectic混合物内的蒸汽压力来调整.
- 生物基膜表现出适合作为治疗贴片的潜在用途的性能.
结论:
- 基于薄荷醇的HES是先进的烯酸材料的可行,多功能和可持续的增塑剂.
- 这项研究为聚合物行业的环保替代品铺平了道路.
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