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Updated: Jan 16, 2026

Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
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Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction

Published on: April 10, 2018

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一种催化生成的过渡金属模拟的西蒙斯-史密斯反应剂

Jacob Werth1, Kristen Berger1, Christopher Uyeda1

  • 1Department of Chemistry, Purdue University, 560 Oval Drive, West Lafayette, Indiana 47907, United States.

Tetrahedron
|January 15, 2026
PubMed
概括

金二胺 (PDI) 复合物通过一个阴离子 (PDI) Co ((CH2Br) 中间体催化基环,像西蒙斯-史密斯试剂一样起作用. 这种机制解释了ZnBr2的作用,与传统方法相比,它具有明显的选择性.

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Alkynes can be reduced to trans-alkenes using sodium or lithium in liquid ammonia. The reaction, known as dissolving metal reduction, proceeds with an anti addition of hydrogen across the carbon–carbon triple bond to form the trans product. Since ammonia exists as a gas (bp = −33°C) at room temperature, the reaction is carried out at low temperatures using a mixture of dry ice (sublimes at −78°C) and acetone. 
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