设计无法控制的:通过连贯和不连贯的控制来控制杂的旋转相关的根基对
Farhan T Chowdhury1,2,3, Luke D Smith1,2, Daniel R Kattnig1,2
1Department of Physics and Astronomy, University of Exeter, Stocker Road, Exeter EX4 4QL, United Kingdom.
The Journal of chemical physics
|January 15, 2026
概括
研究人员使用Pontryagin最大原理 (PMP) 开发了一种控制工程方法,以精确地管理基数对中的量子自旋动力学. 这种方法为分子量子技术提供了强大的控制,即使有噪音.
科学领域:
- 量子控制是一种量子控制.
- 分子量子技术是分子量子技术.
- 旋转动力学 旋转动力学
背景情况:
- 控制旋转相关的基因对是分子量子技术的关键.
- 由于开放量子系统中复杂的自旋动力学和放松,精确的控制具有挑战性.
- 目前使用Liouville空间传播器的方法对于大型系统是计算不可行的.
研究的目的:
- 为大型,复杂的开放量子系统开发一种可处理的方法,以数值获得控制.
- 展示最佳控制理论的应用,以指导根基对中的旋转动力学.
- 为了在存在噪声时能够对根对旋转动态进行强大的量子控制.
主要方法:
- 应用基于庞特里亚金最大原则 (PMP) 的控制工程方法.
- 数字模拟与旋转相关的根基对动态.
- 开发PMP最佳控制策略的开发.
主要成果:
- 成功地应用PMP-最佳控制来引导连贯和不连贯的旋转动态.
- 对于面临噪声的原型根对模型的稳健控制的演示.
- 对于大型自旋系统来说,这是对计算上不可行的方法的可行的替代方案.
结论:
- 基于PMP的控制工程方法为控制复杂的开放量子系统提供了可行的解决方案.
- 这种方法可以对根对旋转动态进行强大的量子控制,解决噪声挑战.
- 在分子量子技术中为不连贯的控制策略铺平了道路.
相关概念视频
Radical Formation: Overview
2.6K
A bond can be broken either by heterolytic bond cleavage to form ions or homolytic bond cleavage to yield radicals. A fishhook arrow is used to represent the motion of a single electron in homolytic bond cleavage. There are two main sources from which radicals can be formed:
Radicals from spin-paired molecules:
Radicals can be obtained from spin-paired molecules either by homolysis or electron transfer. While two radicals are formed in the former, an electron is added in the...
Radicals from spin-paired molecules:
Radicals can be obtained from spin-paired molecules either by homolysis or electron transfer. While two radicals are formed in the former, an electron is added in the...
2.6K
Spin–Spin Coupling Constant: Overview
1.5K
In bromoethane, the three methyl protons are coupled to the two methylene protons that are three bonds away. In accordance with the n+1 rule, the signal from the methyl protons is split into three peaks with 1:2:1 relative intensities. The methylene protons appear as a quartet, with the relative intensities of 1:3:3:1.
Qualitatively, any spin plus-half nucleus polarizes the spins of its electrons to the minus-half state. Consequently, the paired electron in the hydrogen–carbon bond must...
Qualitatively, any spin plus-half nucleus polarizes the spins of its electrons to the minus-half state. Consequently, the paired electron in the hydrogen–carbon bond must...
1.5K
Radial System Protection
420
Radial systems employ time-delay overcurrent relays to reduce load interruptions. When a fault occurs, the nearest breaker opens first, while upstream breakers remain closed due to longer delay settings. This approach ensures minimal disruption to the rest of the system.
In a radial system with a fault downstream of the third breaker, ideally, only the third breaker will open, isolating the fault and interrupting the load connected beyond it. The second breaker has a longer delay setting,...
In a radial system with a fault downstream of the third breaker, ideally, only the third breaker will open, isolating the fault and interrupting the load connected beyond it. The second breaker has a longer delay setting,...
420
Control Systems
1.8K
Control systems are everywhere in contemporary society, influencing diverse applications from aerospace to automated manufacturing. These systems can be found naturally within biological processes, such as blood sugar regulation and heart rate adjustment in response to stress, as well as in man-made systems like elevators and automated vehicles. A control system is essentially a network of subsystems and processes that collaboratively convert specific inputs into desired outputs.
At the heart...
At the heart...
1.8K
Feedback control systems
687
Feedback control systems are categorized in various ways based on their design, analysis, and signal types.
Linear feedback systems are theoretical models that simplify analysis and design. These systems operate under the principle that their output is directly proportional to their input within certain ranges. For instance, an amplifier in a control system behaves linearly as long as the input signal remains within a specific range. However, most physical systems exhibit inherent nonlinearity...
Linear feedback systems are theoretical models that simplify analysis and design. These systems operate under the principle that their output is directly proportional to their input within certain ranges. For instance, an amplifier in a control system behaves linearly as long as the input signal remains within a specific range. However, most physical systems exhibit inherent nonlinearity...
687
Radical Reactivity: Overview
2.6K
Radicals, the highly reactive species, gain stability by undergoing three different reactions. The first reaction involves a radical-radical coupling, in which a radical combines with another radical, forming a spin‐paired molecule. The second reaction is between a radical and a spin‐paired molecule, generating a new radical and a new spin‐paired molecule. The third reaction is radical decomposition in a unimolecular reaction, forming a new radical and a spin‐paired...
2.6K


