在形成过程中对一个没有的丰富的多层氧化物阴极的结构重组
Matteo Busato1,2, Mariarosaria Tuccillo1,2,3, Arcangelo Celeste1,2,3
1Department of Chemistry, Sapienza University of Rome, P.le Aldo Moro 5, 00185 Rome, Italy.
概括
富层氧化物 (LRLO) 阴极材料的初始循环,特别是Co-free,Ni-poor类型,引发了对稳定的电池性能至关重要的结构变化. 这项研究揭示了一种独特的激活途径,使其具有高容量和可逆性而不会降解.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 固态化学 固态化学
背景情况:
- 富层氧化物 (LRLO) 阴极材料中的第一循环形成对于相间巩固和长期循环能力至关重要.
- 形成过程中的特定结构和组成变化是物质依赖的,对于无可,无贫的LRLOs来说并不清楚.
研究的目的:
- 分析一个具有代表性的无Co,无Ni的LRLO (Li 1.28Ni 0.15Mn 0.57O 2) 的形成过程,以了解其激活途径.
- 阐明结构和格子变化,使这种重要的类型的阴极材料能够稳定循环.
主要方法:
- 结合电化学,运行质谱,X射线衍射 (XRD) 和X射线吸收光谱 (XAS).
- 用密度函数理论 (DFT) 模拟来补充实验发现.
主要成果:
- 激活显著压缩*c*轴层间距,并增强可逆结构呼吸.
- 高容量 (~250 mAh g-1) 来自合的Ni和O氧化还原过程,O-氧化还原发生在整个离子子子网中.
- 由顺序的Ni和O氧化还原驱动的MnO6八面体的不可逆转的结构演化,使得在没有有害的氧化演化的情况下实现了卓越的电化学性能.
结论:
- 已经确定了Co-free,Ni-poor LRLOs的一个独特的激活途径,其特征是显著的结构和晶格变化.
- 这一途径促进了可逆的O-redox,并使高容量和稳定性成为可能,这对于下一代电池至关重要.
- 这些发现为设计具有改进的电化学性能的先进,可持续的阴极材料提供了指导.
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