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Updated: Jan 20, 2026

Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
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Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework

Published on: April 9, 2018

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[S©Cd5S5]2-:一个平面五坐标的硫二离子,由过渡金属框架稳定

Xin-Bo Liu1, Yu-le Dou1, Xiao-Han Yin1

  • 1Institute of Atomic and Molecular Physics, Jilin University, Changchun 130023, China. zcui@jlu.edu.cn.

Dalton transactions (Cambridge, England : 2003)
|January 19, 2026
PubMed
概括

研究人员设计了新的平面高坐标星团. 该研究发现了一种高度稳定的平面五坐标硫二,[S©Cd5S5]2-,为硫化学提供了新的途径.

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Transition Metals: Electron Configurations and Properties02:58

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Through the sulfurization of pre-deposited transition metals, large-area and vertical 2D crystal hetero-structures can be fabricated. The film transferring and device fabrication procedures are also demonstrated in this...
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Transition metals are defined as those elements that have partially filled d orbitals. As shown in Figure 1, the d-block elements in groups 3–12 are transition elements. The f-block elements, also called inner transition metals (the lanthanides and actinides), also meet this criterion because the d orbital is partially occupied before the f orbitals.
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