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Updated: Jan 21, 2026

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通过使用分子氧的多氧酸基MOF催化的氨基醇合成氨基酸的环保合成

Hui Chen1, Hongrui Tian1, Yubing Sui1

  • 1School of Petrochemical Engineering, Liaoning Petrochemical University, Fushun 113001, China.

Inorganic chemistry
|January 19, 2026
PubMed
概括

新的多氧瓦纳酸-框架有效地利用分子氧气催化氨基氧 (APXOs) 的合成. 这种绿色化学方法证明了制药应用的高产量,可回收性和可扩展性.

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Base-Catalyzed Ring-Opening of Epoxides

Due to their highly strained structures, epoxides can readily undergo ring-opening reactions through nucleophilic substitution, either in the presence of an acid or a base. The nucleophilic substitution reactions in the presence of acid are called acid-catalyzed ring-opening reactions, and nucleophilic substitution reactions in the presence of a base are called base-catalyzed ring-opening reactions. Epoxides undergo base-catalyzed ring-opening reactions in the presence of a strong nucleophile...
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Overview
Dehydration synthesis (also called a condensation reaction) is the chemical process in which two molecules covalently link together to form a new molecule, along with the release of a water molecule. Many physiologically important compounds form by dehydration synthesis reactions, such as complex carbohydrates, proteins, DNA, and RNA.
Synthesis of carbohydrates
Sugar molecules are covalently linked together by dehydration synthesis. During the reaction, the hydroxyl (-OH) group from...
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