在高度酸性条件下,同时氧化硫化物和减少硫酸盐,用于细胞内氧化还原恒温
Tipei Jia1, Yongzhen Peng2, Lishan Niu1
1State Key Laboratory of Regional Environment and Sustainability, School of Environment, Tsinghua University, Beijing, China.
Nature communications
|January 19, 2026
概括
某些细菌可以同时进行硫化物氧化和硫酸盐减少,这挑战了以前的科学理解. 这一双重过程有助于排毒有害的硫化物,并在极端环境中保持细胞平衡.
科学领域:
- 微生物生态学 微生物生态学
- 生物地质化学循环的过程
- 生物化学 生物化学
背景情况:
- 硫化物氧化和硫酸盐减少是微生物硫循环的关键过程.
- 这些相反的反应通常是分开的,以防止徒劳的循环.
研究的目的:
- 为了研究Mycobacterium sp.的硫代谢. 在特定的环境条件下MAG-M116.
- 挑战分离硫化物氧化和硫酸盐还原的范式.
主要方法:
- 隔离和表征的 菌株 Mycobacterium sp. 的 MAG-M116来自生物硫化系统.
- 在有氧,低pH,富含硫酸盐和H2S过载条件下的代谢途径分析.
主要成果:
- 这种细菌是Mycobacterium sp. MAG-M116同时进行硫化物氧化和同化硫酸盐减少 (ASR).
- 硫化物氧化通过前向和反向电子转移产生ATP和NADPH.
- ASR充当氧化还原恒温器,捕获电子以减少57.5%的活性氧物种.
结论:
- 结合对立的氧化还原反应代表了维持细胞内氧化还原平衡的适应性策略.
- 这种双向的硫代谢允许Mycobacterium在基质过剩条件下主导其环境.
相关概念视频
Oxidation-Reduction Reactions
75.1K
Oxidation–Reduction Reactions
75.1K
Balancing Redox Equations
61.7K
Electrochemistry is the science involved in the interconversion of electrical and chemical reactions. Such reactions are called reduction-oxidation, or redox reactions. These important reactions are defined by changes in oxidation states for one or more reactant elements and include a subset of reactions involving the transfer of electrons between reactant species. Electrochemistry as a field has evolved to yield sufficient insights on the fundamental principles of redox chemistry and multiple...
61.7K
Redox Reactions
58.4K
Oxidation-reduction or redox reactions involve the transfer of electrons from one molecule or atom to another. When an atom gains an electron, another atom must lose an electron, meaning oxidation and reduction must occur together. Since the redox occurs in pairs, the atom that gets oxidized is also called the reducing agent or reductant, and the atom that is reduced is also called the oxidizing agent or oxidant. A straightforward way to remember the definitions of oxidation and reduction is...
58.4K
Redox Titration: Other Oxidizing and Reducing Agents
1.4K
Besides iodine, other oxidizing or reducing agents can serve as titrants in redox titrations. Common oxidizing titrants include KMnO4, cerium(IV), and K2Cr2O7. The choice of oxidizing titrants depends on factors like stability, cost, analyte strength, and reaction rate between the analyte and titrant. KMnO4 is a strong oxidizing titrant that reduces from Mn(VII) to Mn(II) in a highly acidic solution, simultaneously oxidizing the analyte to a higher oxidation state. In this case, KMnO4 acts as a...
1.4K
Oxidation and Reduction of Organic Molecules
9.1K
Energy production within a cell involves many coordinated chemical pathways. Most of these pathways are combinations of oxidation and reduction reactions, which occur at the same time. An oxidation reaction strips an electron from an atom in a compound, and the addition of this electron to another compound is a reduction reaction. Because oxidation and reduction usually occur together, these pairs of reactions are called redox reactions.
The removal of an electron from a molecule, results in a...
The removal of an electron from a molecule, results in a...
9.1K
Oxidation Numbers
42.2K
In redox reactions, the transfer of electrons occurs between reacting species. Electron transfer is described by a hypothetical number called the oxidation number (or oxidation state). It represents the effective charge of an atom or element, which is assigned using a set of rules.
42.2K


