竞争性Ni/Mn减少和微电流合的负热膨胀在脱化丰富的阴极中
Jilu Zhang1,2, Qin Wang1,3, Xinyue Zhai1
1School of Chemical Engineering and Technology, State Key Laboratory of Electrical Insulation and Power Equipment, School of Instrument Science and Technology, Xi'an Jiaotong University, No.28, West Xianning Road, Xi'an, 710049, China.
Angewandte Chemie (International ed. in English)
|January 20, 2026
概括
富含的分层氧化物阴极 (LRLOs) 对高容量的离子电池具有前景. 这项研究揭示了它们在加热过程中的热行为和结构变化,这对于提高电池安全至关重要.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 电池技术 电池技术
背景情况:
- 高能量密度的需求推动了对富含的基于Mn的分层氧化物阴极 (LRLOs) 的兴趣.
- 由于高压运行,热逃跑是LRLOs的关键安全问题.
- 在加热过程中脱化LRLOs的结构演变机制尚不清楚.
研究的目的:
- 为了研究Li1.2Ni0.2Mn0.6O2 (LLNMO) 在不同电荷-放电状态的加热过程中的结构和化学演变.
- 为了阐明LRLOs的热失控机制.
- 为设计更安全的LRLO材料提供见解.
主要方法:
- 在现场高温X射线衍射.
- 在现场高温X射线吸收光谱.
- 在不同的充放电状态中进行系统的调查.
主要成果:
- 在LLNMO的充电状态下加热时, (Ni) 减少首先发生.
- (Mn) 减少,晶格氧气损失和相位过渡到无序的分层或岩盐相位发生在更高的温度下.
- 在初始循环后,LLNMO表现出低于200°C的负热膨胀,这是由于微链和结构排序造成的.
结论:
- 这项研究提供了对丰富的多层材料的电荷状态依赖的热行为的机械洞察.
- 这些发现为开发更安全,更高容量的LRLO电池材料提供了指导方针.
- 了解热演变是减轻先进离子电池中热失控风险的关键.
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