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相关概念视频

Network Covalent Solids02:18

Network Covalent Solids

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Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
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Covalent Bonds01:29

Covalent Bonds

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Overview
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Covalent Bonds01:08

Covalent Bonds

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When two atoms share electrons to complete their valence shells, they create a covalent bond. An atom's electronegativity—the force with which shared electrons are pulled towards an atom—determines how the electrons are shared. Molecules formed with covalent bonds can be either polar or nonpolar. Atoms with similar electronegativities form nonpolar covalent bonds; the electrons are shared equally. Atoms with different electronegativities share electrons unequally,...
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Covalently Linked Protein Regulators02:04

Covalently Linked Protein Regulators

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Proteins can undergo many types of post-translational modifications, often in response to changes in their environment. These modifications play an important role in the function and stability of these proteins. Covalently linked molecules include functional groups, such as methyl, acetyl, and phosphate groups, and also small proteins, such as ubiquitin. There are around 200 different types of covalent regulators that have been identified.
These groups modify specific amino acids in a protein....
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Covalent Bonding and Lewis Structures02:46

Covalent Bonding and Lewis Structures

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Compared to ionic bonds, which results from the transfer of electrons between metallic and nonmetallic atoms, covalent bonds result from the mutual attraction of atoms for a “shared” pair of electrons.
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What is a Mode?01:07

What is a Mode?

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The mode is one of the commonly used measures of a central tendency. It is defined as the most frequent value in a data set.
There can be more than one mode in a data set if multiple values have the same highest frequency. For instance, suppose that the Statistics exam scores of 20 students are: 50; 53; 59; 59; 63; 63; 72; 72; 72; 72; 72; 76; 78; 81; 83; 84; 84; 84; 90; 93. Here, the mode is 72, as it occurs most frequently, five times.
A data set with two modes is called bimodal. For example,...
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相关实验视频

Updated: Jan 22, 2026

Dual-mode Imaging of Cutaneous Tissue Oxygenation and Vascular Function
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具有双模式功能的机器集成的三维共价有机框架

Junxia Ren1, Yujie Wang2,3, Jinquan Suo1

  • 1State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, P. R. China.

Journal of the American Chemical Society
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概括
此摘要是机器生成的。

研究人员通过将分子电机嵌入到共价有机框架 (COF) 中,创造了一种新材料. 这项创新使得光控制的二氧化碳捕获和药物输送成为可能,

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科学领域:

  • 材料科学
  • 超分子化学
  • 纳米技术

背景情况:

  • 生物系统在支架内使用分子机器进行宏观功能.
  • 合成复制需要将分子电机整合到动态,有序的框架中.

研究的目的:

  • 为将过度拥挤的旋电机纳入3D共价有机框架 (COF) 制定一个网状设计策略.
  • 创建一个原型材料 (JUC-666),展示协调的分子运动和宏观功能.

主要方法:

  • 包含过度拥挤的旋电机的3D共价有机框架 (COF) 的网状合成.
  • 在溶液和固体状态下进行光谱和运动分析以确认单向电机旋转.
  • 评估二氧化碳吸收调节和光控制的药物释放功能.

主要成果:

  • 成功将旋转电机纳入具有单向旋转的3D COF (JUC-666).
  • 通过光暗循环证明可逆的二氧化碳吸收调节 (在273K时83%的容量变化).
  • 达到精确控制的药物释放与光剂量相称的动力学 (累计释放的∼50倍增加).

结论:

  • 共价有机框架 (COF) 可以有效地将分子级运动与宏观反应联系起来.
  • JUC-666作为设计具有双模式能力的适应性功能材料的平台.
  • 这种方法可以开发出对外刺激如光等有反应的材料.