具有双模式功能的机器集成的三维共价有机框架
Junxia Ren1, Yujie Wang2,3, Jinquan Suo1
1State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, P. R. China.
Journal of the American Chemical Society
|January 20, 2026
概括
研究人员通过将分子电机嵌入到共价有机框架 (COF) 中,创造了一种新材料. 这项创新使得光控制的二氧化碳捕获和药物输送成为可能,
科学领域:
- 材料科学
- 超分子化学
- 纳米技术
背景情况:
- 生物系统在支架内使用分子机器进行宏观功能.
- 合成复制需要将分子电机整合到动态,有序的框架中.
研究的目的:
- 为将过度拥挤的旋电机纳入3D共价有机框架 (COF) 制定一个网状设计策略.
- 创建一个原型材料 (JUC-666),展示协调的分子运动和宏观功能.
主要方法:
- 包含过度拥挤的旋电机的3D共价有机框架 (COF) 的网状合成.
- 在溶液和固体状态下进行光谱和运动分析以确认单向电机旋转.
- 评估二氧化碳吸收调节和光控制的药物释放功能.
主要成果:
- 成功将旋转电机纳入具有单向旋转的3D COF (JUC-666).
- 通过光暗循环证明可逆的二氧化碳吸收调节 (在273K时83%的容量变化).
- 达到精确控制的药物释放与光剂量相称的动力学 (累计释放的∼50倍增加).
结论:
- 共价有机框架 (COF) 可以有效地将分子级运动与宏观反应联系起来.
- JUC-666作为设计具有双模式能力的适应性功能材料的平台.
- 这种方法可以开发出对外刺激如光等有反应的材料.
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