含有稀土元素的纳米颗粒从中国多个工业中释放出来的大气概况和空间分布
Qiuting Yang1, Lili Yang2, Jianghui Yun2
1Zhejiang Key Laboratory of Digital Intelligence Monitoring and Restoration of Watershed Environment, College of Geography and Environmental Sciences, Zhejiang Normal University, Jinhua 321004, China; State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, P.O. Box 2871, Beijing 100085, China.
稀土元素 (REEs) 是有毒的. 这项研究量化了工业排放中含有REE的纳米粒子 (NP),发现燃煤发电厂是主要的排放者,增加了大气中的NP度和人类潜在暴露.
科学领域:
- 环境科学 环境科学
- 毒理学 毒理学 毒理学
- 纳米技术纳米技术
背景情况:
- 稀土元素 (REEs) 具有毒性和环境危害.
- 关于工业排放中的REE质量度的数据有限.
- 纳米粒子 (NP) 毒性取决于粒子数度 (PNC),而不仅仅是质量.
研究的目的:
- 来自各种工业来源的含有REE的NP排放量.
- 确定含有REE的NPs的主要工业排放者.
- 评估这些排放对大气度和人类暴露的影响.
主要方法:
- 分析了来自13个工业部门的132个工业颗粒物 (PM) 样本.
- 含有REE的量化NP排放量及其PNC.
- 计算了大气稳定状态度和终身平均每日剂量 (LADD).
主要成果:
- (Ce) 和兰 (La) 是最丰富的REEs.
- 燃煤发电厂 (CFPP) 在含有Ce的NP中显示了最高的PNC (1.9 x 10^10颗粒/g).
- 制炉,水泥炉,焦化工和钢铁工业是大气中含有La和Ce的NP的重要排放者.
结论:
- 工业排放大大增加了大气中含有La和Ce的NP度.
- 计算的LADD表明通过吸入和皮肤途径对人类的大量暴露.
- 强调需要评估REE-NP排放量,以实现可持续的工业发展.
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