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相关概念视频

Trends in Lattice Energy: Ion Size and Charge02:54

Trends in Lattice Energy: Ion Size and Charge

26.5K
An ionic compound is stable because of the electrostatic attraction between its positive and negative ions. The lattice energy of a compound is a measure of the strength of this attraction. The lattice energy (ΔHlattice) of an ionic compound is defined as the energy required to separate one mole of the solid into its component gaseous ions. For the ionic solid sodium chloride, the lattice energy is the enthalpy change of the process:
26.5K
Ions and Ionic Charges03:27

Ions and Ionic Charges

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In ordinary chemical reactions, the nucleus — which contains the protons and neutrons of each atom and thus identifies the element — remains unchanged. Electrons, however, can be added to atoms by transfer from other atoms, lost by transfer to other atoms, or shared with other atoms. The transfer and sharing of electrons among atoms govern the chemistry of the elements. During the formation of some compounds, atoms gain or lose electrons to form electrically charged particles called...
78.6K
Network Covalent Solids02:18

Network Covalent Solids

16.1K
Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
16.1K
Batteries and Fuel Cells03:12

Batteries and Fuel Cells

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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
30.8K
Atomic Radii and Effective Nuclear Charge03:08

Atomic Radii and Effective Nuclear Charge

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The elements in groups of the periodic table exhibit similar chemical behavior. This similarity occurs because the members of a group have the same number and distribution of electrons in their valence shells.
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Molecular and Ionic Solids02:54

Molecular and Ionic Solids

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Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
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相关实验视频

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Non-aqueous Electrode Processing and Construction of Lithium-ion Coin Cells
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快速充电的离子袋式电池通过在紧的阴极中构建固相导电网络.

Guangying Wan1,2, Guibin Zan3, Doug Rowland3

  • 1College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China.

ACS applied materials & interfaces
|January 20, 2026
PubMed
概括

研究人员通过创建固相 (Li) 导电网络,增强了离子电池 (LIB) 的快速充电. 这一策略改善了压缩阴极中的离子扩散,克服了高速电池操作的局限性.

关键词:
离子电池是一种离子电池.电脑断层扫描X射线扫描压缩的阴极是压缩的.快速充电 快速充电 快速充电固体相液体导电网络 固体相液体导电网络

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相关实验视频

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Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques
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科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 储能 储能 储能 储能 储能 储能

背景情况:

  • 离子电池 (LIB) 的快速充电受到压缩阴极中的离子扩散的限制.
  • 高密度电极中的电解质透性差,阻碍了高速性能.

研究的目的:

  • 开发一种改进压缩LIB阴极中的离子扩散的方法.
  • 为了使高体积能量密度LIBs的快速充电能力.

主要方法:

  • 加入Li$_{6.4}$La$_{3}$Zr$_{1.4}$Ta$_{0.6}$O$_{12}$作为固体相Li-导电添加剂.作为固体相Li-导电添加剂.
  • 使用X射线计算机断层扫描来分析离子运输机制.
  • 在离子袋式电池中对改性压缩阴极进行电化学测试.

主要成果:

  • 修改后的阴极与导网保持了97.9mAh的特定容量g$^{-1}$以5C的速度.
  • 添加剂促进了离子运输,防止在未经修改的正极中观察到的电化学故障.
  • 在实用的离子袋式电池中成功演示使用厚厚,紧的阴极.

结论:

  • 构建固相导电网是一种有效的策略,可以在压缩的LIB阴极中增强快速充电.
  • 调整的运输通路可以克服电解质透的限制.
  • 这种方法有可能推进高速率的储能解决方案.