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Updated: Jan 23, 2026

Synthesis of a Borylated Ibuprofen Derivative Through Suzuki Cross-Coupling and Alkene Boracarboxylation Reactions
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通过吸附调制进行电化学C-N合:选择性合成生物质衍生的5-基甲基酸胺的氨基

Dingbo Lai1,2, Jia Yu1,2, Zi-Ang Ma1,2

  • 1School of Chemical Engineering & Technology, Key Laboratory for Green Chemical Technology of Ministry of Education, Tianjin University, Collaborative Innovation Center for Chemical Science & Engineering, Tianjin, 300350, China.

Nature communications
|January 21, 2026
PubMed
概括

量身定制的白银 (Ag) 催化剂表面增强了5-基甲基 (HMF) 与甲基胺的电化学C-N合. Ag111) 方面通过优化HMF吸附和化,提高了可持续氨基生产的选择性.

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Direct alkylation of ammonia produces polyalkylated amines, along with a quaternary ammonium salt. To exclusively prepare primary amines, the azide synthesis method can be used.
Azide ions act as good nucleophiles and react with unhindered alkyl halides to form alkyl azides. Alkyl azides do not participate in further nucleophilic substitution reactions, thereby eliminating the chances of polyalkylated products. Alkyl azides are reduced by hydride-based reducing agents, like lithium aluminum...
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