利用可逆的0D-1D转化在化的化中,用于智能循环极化发光切换和多级加密
Jinyang Li1, Kele Liao1, Qinghong Zeng1
1Key Laboratory of Theoretical & Computational Photochemistry of Ministry of Education, College of Chemistry, Beijing Normal University, Beijing, 100875, China.
Angewandte Chemie (International ed. in English)
|January 22, 2026
概括
研究人员开发了新的合混合化物材料,这些材料表现出可调节的循环极化发光 (CPL). 这些材料可以在响应刺激时将CPL颜色从绿色转变为红色,从而实现先进的光子加密.
科学领域:
- 材料科学 材料科学 材料科学
- 固态化学 固态化学
- 光子学 是一个光子学.
背景情况:
- 动态调节的循环极化发光 (CPL) 材料对于先进的光子学和加密至关重要.
- 为CPL调实现可预测的固态结构转换仍然具有挑战性.
研究的目的:
- 为了证明一个维度工程策略的刺激响应CPL在合混合Mn{\displaystyle Mn{\text{II}}) 化物.
- 开发基于CPL属性的多层光子加密平台.
主要方法:
- 选择性合成不同的1D和0D阶段,使用一种奇拉性阴离子 (R/S-3-methylmorpholine).
- 研究了在0D和1D阶段之间以乙醇辅助的热转换.
- 设计了一个使用CPL切换的多层光子加密平台.
主要成果:
- 合成了发出红色的1D和发出绿色的0D合杂交的Mn (II) 化物相.
- 在乙醇诱导的热刺激后,观察到0D阶段快速,可逆地转化为1D阶段.
- 在相位转换过程中表现出明显的CPL颜色从绿色转变为红色.
- 成功实施了一种复杂的多层次光子加密系统.
结论:
- 结构维度控制是设计智能,CPL活性材料的强大策略.
- 可逆的,对刺激有反应的CPL行为为高安全的光学信息技术开辟了新的可能性.
- 这项工作推动了用于安全数据编码和光通信的先进材料的开发.
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