在Fe/Cr替代的Nd2Co17化合物中通过磁弹性合来调节负热膨胀
Jiayuan Li1,2, Chenfei Qv2, Haoran Tu1
1Center for Neutron Scattering and Advanced Light Source Science and Technology, Dongguan University of Technology, Dongguan, P. R. China.
Advanced science (Weinheim, Baden-Wurttemberg, Germany)
|January 23, 2026
概括
我们开发了一种新的磁弹性方法来控制稀土金属间化合物的热膨胀. 这种方法可以为高精度应用提供可调整的正负热膨胀 (NTE).
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 磁力学 磁力学 是一种
背景情况:
- 精确调节的热膨胀对于高精度应用至关重要.
- 通过组合控制实现正和负热膨胀 (NTE) 之间的双向切换仍然是一个挑战.
研究的目的:
- 介绍一种磁弹性方法,用于调整 Nd2(Co1-xFex) 17-yCry 化合物的异型热膨胀.
- 为了研究积极和消极热膨胀之间的组成依赖的切换.
主要方法:
- 使用同步射线X射线衍射来研究格子响应.
- 进行了Nd2(Co1-xFex) 17-yCry化合物的组合调.
- 临界指数分析是在基里温度 (TC) 附近进行的.
主要成果:
- 富含铁的组合物在TC以下的c轴 (αc = -5.23 × 10^-6 K^-1) 上表现出单轴NTE.
- 这种NTE归因于强大的磁弹性合和增强的负交换相互作用.
- 组合调节抑制了体积膨胀系数和调节的TC (442625K).
结论:
- 建立了一个新的战略,以实现稀土金属间金属的零或接近零的热膨胀.
- 这些材料在精密热管理应用中显示出前途.
- 这些发现突出了磁弹性合和磁相互作用在控制热膨胀中的作用.
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