使用四甲基氧化进行性提取,用CV-MIP AES测定鱼样中的,作为传统样品制备方法的替代方案
Fiorella Iaquinta1,2, Alicia Mollo2
1Grupo de Química Analítica Ambiental, Facultad de Química, Universidad de la República, Uruguay.
Analytical methods : advancing methods and applications
|January 23, 2026
概括
使用四甲基氧化 (TMAH) 的提取的新方法允许在鱼类中确定. 这种环保的方法为评估海鲜中的含量提供了一个安全的替代方案.
科学领域:
- 环境化学环境化学
- 分析化学 分析化学
- 食品安全 食品安全
背景情况:
- (Hg) 在水生生态系统中生物放大,通过食用海鲜对人类构成毒性风险.
- 准确确定鱼类中的含量对于确保人类健康和食品安全至关重要.
研究的目的:
- 开发和验证一种用于鱼样中的新方法.
- 评估使用四甲基氧化 (TMAH) 作为传统酸性消化方法的替代品的性提取方法.
主要方法:
- 使用TMAH从鱼样中的性提取,然后在一夜之间进行化.
- 中和,用酸 (HNO3) 酸化,最后调整体积.
- 使用冷蒸汽 - 干扰 - 掩盖原子发射光谱法 (CV-MIP AES) 量化,使用玻化 (NaBH4) 作为减少剂.
主要成果:
- 该方法实现了0.0029毫克/kg-1的检测极限和0.0096毫克/kg-1.1的量化极限.
- 线性范围为1.3-10.4μg L-1 ,可重复性精度为13.3%.
- 建议方法的结果在统计学上相当于常见的酸性微波辅助消化方法.
结论:
- 开发的使用提取的CV-MIP AES方法是一种可靠和敏感的技术,用于鱼类中的测定.
- 这种方法为传统的酸性消化技术提供了一种易于操作和环保的替代方案.
- 通过准确测量含量,确保了供人食用的水产食品的安全.
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