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在工业尺寸可逆固体氧化物电池中的高性能氧气电极中,B-Site Fe-Co-Ni 三重兴奋剂
Bin Li1,2, Hao Xiong1, Guangying Chen3
1Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan, China.
一种新的矿氧化物LCFNC增强了可逆固体氧化物细胞 (RSOC) 的氧气电极. 它提供了更好的活性,稳定性和热膨胀匹配,使得高效的工业规模的RSOC应用成为可能.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 能源转化和储存 能源转化和储存
背景情况:
- 可逆固体氧化物电池 (RSOCs) 中的氧电极面临着挑战,包括低催化活性,不稳定性和热膨胀系数 (TEC) 与电解质不匹配.
- 开发先进的电极材料对于提高RSOC性能和实现实际应用至关重要.
研究的目的:
- 设计和合成一种新的矿氧化物La0.6Ca0.4Fe0.8Ni0.1Co0.1O3-δ (LCFNC),以提高RSOC中的氧气电极性能.
- 对LCFNC的催化活性,稳定性和热兼容性研究协同兴奋剂的影响.
- 评估LCFNC在燃料电池和电解模式中的性能,包括工业规模的设备.
主要方法:
- 采用多元元素B位点协同兴奋剂策略,合成了新型矿氧化物LCFNC.
- 系统地描述LCFNC的结构,热和电化学特性.
- 在燃料电池和电解模式下进行全电池性能测试,包括稳定性评估和工业规模设备评估.
主要成果:
- LCFNC表现出抑制的TEC (12.7 × 10-6 K-1 与GDC),确保了优异的电解质兼容性.
- 协同兴奋剂产生了三元活性中心,增强了表面氧空隙度和催化活性.
- 在800°C时,在1.3V (电解模式) 达到1.60W·cm-2 (FC模式) 和1.82A·cm-2的峰值功率密度.
- 经过100小时的电解和24个可逆周期,证明了极好的稳定性.
- 工业尺寸的RSOC (15 × 15cm2) 在800°C下提供64W (FC模式) 和105A (电解模式).
结论:
- 多元元素B位点兴奋剂是一种有效的策略,用于开发RSOC的高性能氧电极材料.
- 由于其增强的活性,稳定性和兼容性,LCFNC为推进高性能RSOC的实际应用提供了一个有前途的解决方案.
- 该研究为未来的氧气电极材料开发提供了机械的理解和设计原则.
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