与碳共同结晶的过程
Jogirdas Vainauskas1,2, Tomislav Friščić1,2
1School of Chemistry, University of Birmingham, Edgbaston, Birmingham B152TT, UK. t.friscic@bham.ac.uk.
概括
碳 碳 碳 碳 碳 碳
科学领域:
- 超分子化学 超分子化学
- 材料化学 材料化学
- 有机合成 有机合成
背景情况:
- 与和氧相比,碳在超分子相互作用中的作用尚未得到充分研究.
- 现有的研究往往忽略了以碳为基础的部分作为关键的相互作用场所.
研究的目的:
- 审查使用碳基识别站点设计多组件晶体 (共晶体) 的机会.
- 要突出素结合和涉及碳的C-Hπ相互作用的意义.
- 展示碳在固态超分子化学中的作用.
主要方法:
- 关于共同结晶中的碳的历史和最近文献的综述.
- 专注于非替代的多环芳 (PAH),单碳功能 (异二,碳) 和元素碳 (富勒烯).
- 重点是素结合和C-Hπ相互作用.
主要成果:
- 基于碳的部分,包括PAH,异二烯,碳和富勒伦,可以有效地用于共晶设计.
- 素结合和C-Hπ相互作用对于识别基于碳的识别站点至关重要.
- 应用范围从基础研究和材料设计到生物分子识别和外星地质学.
结论:
- 碳在固态超分子化学和共结晶中起着重要的,但往往被低估的作用.
- 设计与碳分子的相互作用,为材料科学及其他领域开辟了新的途径.
- 对碳的超分子能力进行进一步的探索对于各种应用是有必要的.
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