海洋沉积物中的Y/Ho比率揭示了新新生代海洋酸化
Yong-Sheng Liu1, Wen-Shuai Li2, Jun-Bo Zhang3
1YU-CUGW Joint Research Center on Deep Earth and Surface Dynamic Coupling, Yangtze University, Wuhan 430110, China; State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Wuhan 430074, China; School of Earth Sciences, China University of Geosciences, Wuhan 430074, China.
Science bulletin
|January 24, 2026
概括
沉积物中的/ (Y/Ho) 分割是古代海洋的新pH代理. 这种方法揭示了长期的前坎布里亚时期海洋酸化,挑战了以前对中性到性条件的估计.
科学领域:
- 地质化学 地质化学
- 古海洋学是古海洋学.
- 地球科学 地球科学 地球科学
背景情况:
- 前坎布里亚海水的pH值对于了解早期地球生物圈至关重要.
- 由于缺乏可靠的代理数据,定量pH数据是有限的.
研究的目的:
- 为了确定/ (Y/Ho) 分割作为古代海水的新型pH代理.
- 为了重建前坎布里亚时期的海洋pH值,并调查其演变.
主要方法:
- 在对铁质和质沉积物的吸附过程中对Y/Ho分离的实验分析.
- 开发一种使用Y/Ho比率的定量方法来重建古海水pH值.
- 使用现代和法内罗纪沉积物记录验证代理.
主要成果:
- 在铁质沉积物中,Y/Ho 分割表现出 pH 取决于功率定律的关系.
- 在粘土沉积物中,Y/Ho分离是由pH和盐度控制的.
- 代理准确地重建了现代海水的pH值 (例如,太平洋沉积物中的pH值为8.21±0.22).
- 新新生态时期的元皮质和铁构成表明海洋长期酸化 (pH 5.96.4).
结论:
- Y/Ho 分割代理为定量古PH重建提供了一个强大的工具.
- 前坎布里亚时期的海洋经历了长时间的酸化,这与之前的中性到性估计相反.
- 这种酸性状态可能与罗丁亚分裂期间的火山CO2排气有关,影响了早期的海洋化学.
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