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Bonding in Metals02:32

Bonding in Metals

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Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”. 
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Metallic Solids02:37

Metallic Solids

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Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
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Alkali Metals03:06

Alkali Metals

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Group 1 elements are soft and shiny metallic solids. They are malleable, ductile, and good conductors of heat and electricity. The melting points of the alkali metals are unusually low for metals and decrease going down the group, while the density increases going down the group with the exception of potassium (Table 1).
Table 1: Properties of the alkali metals
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Metal-Ligand Bonds02:51

Metal-Ligand Bonds

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The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
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Olefin Metathesis Polymerization: Ring-Opening Metathesis Polymerization (ROMP)01:16

Olefin Metathesis Polymerization: Ring-Opening Metathesis Polymerization (ROMP)

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Ring-opening metathesis polymerization or ROMP involves strained cycloalkenes as starting materials. The mechanism of ROMP proceeds by reacting cycloalkene with Grubbs catalyst to give metallacyclobutane intermediate which undergoes a ring-opening reaction to form new carbene. The new carbene reacts with another molecule of cycloalkene. Repetition of these steps leads to the formation of an unsaturated open-chain polymer product. All these steps are reversible, however, relieving the ring...
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Properties of Transition Metals02:58

Properties of Transition Metals

29.7K
Transition metals are defined as those elements that have partially filled d orbitals. As shown in Figure 1, the d-block elements in groups 3–12 are transition elements. The f-block elements, also called inner transition metals (the lanthanides and actinides), also meet this criterion because the d orbital is partially occupied before the f orbitals.
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Three-Dimensional Printing Guide Template Assisted Percutaneous Vertebroplasty PVP
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使用编程通过打印 (PvP) 控制细胞相容的金属和聚合物纹形态.

Johnson N Agyapong1,2, Teng Zhang1,3, James H Henderson1,2

  • 1Bioinspired Syracuse: Institute for Materials and Living Science, Syracuse University, Syracuse, New York 13244, United States.

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概括
此摘要是机器生成的。

研究人员开发了一种可访问的3D打印方法,以创建形状记忆聚合物 (SMP) 基板,产生可调整的表面纹. 这种技术可以控制潜在的细胞研究的纹模式.

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科学领域:

  • 材料科学 材料科学 材料科学
  • 聚合物科学 聚合物科学
  • 表面工程是什么?表面工程是什么?

背景情况:

  • 像形状记忆聚合物 (SMPs) 等符合条件的基板上的机械不稳定性驱动的纹允许控制的表面地形.
  • 在SMP上产生纹的现有方法往往需要昂贵和复杂的机械执行系统.
  • 需要可访问和民主化的策略来产生各种纹模式.

研究的目的:

  • 开发一种易于使用和易于使用的方法,用于制造能够产生可调节表面纹的SMP基板.
  • 研究基板架构和由此产生的纹形态之间的关系.
  • 为了评估制造的纹表面的细胞相容性.

主要方法:

  • 利用业余爱好者3D打印机和通过打印 (PvP) 编程方法进行单步SMP制造.
  • 通过调整喷嘴温度和直角层数量来控制单轴和双轴收缩.
  • 用金或聚乙烯涂层基板并触发形状记忆效应以诱导纹,其特点是原子力显微镜 (AFM).

主要成果:

  • 制造的SMP基板表现出受控的单轴收缩 (高达40%) 和波桑膨胀 (高达15%).
  • 直角层的数量影响了应变,从对齐到复杂的2D后结构的纹模式过渡.
  • 纹表面显示出C3H10T1/2细胞的高细胞活力 (>90%).

结论:

  • 建立了一个方便且可民主化的3D打印策略,用于在SMP上生成各种表面纹模式.
  • 该方法允许精确控制纹形态,从简单的对齐到复杂的二维图案.
  • 由此产生的纹表面是细胞相容的,表明在细胞研究和组织工程中的潜在应用.