香假体中的活性碳:用于除的合成和吸附研究的多变量优化
Moisés de Souza Luz Faria1, Tatianny de Araujo Andrade1, Renata Pereira Lopes Moreira1
1Department of Chemistry, Federal University of Viçosa, Ave. P.H Rolfs, s/n, Viçosa, MG 36570-900, Brazil.
ACS omega
|January 26, 2026
概括
研究人员从香伪茎中开发出具有高表面积的活性炭,用于酸盐吸附. 优化条件产生了表面积为 2415 m2 g-1 的材料,明显超过了预测.
科学领域:
- 材料科学 材料科学 材料科学
- 环境化学环境化学
- 吸附科学 吸附科学
背景情况:
- 农业废物利用对于可持续实践至关重要.
- 酸盐污染对环境构成重大风险.
- 活性炭是水处理的关键吸附剂.
研究的目的:
- 从香伪茎中合成高表面积活性炭.
- 使用中央复合回转设计 (CCRD) 来优化酸盐吸附的合成条件.
- 描述吸附剂并评估其酸盐吸附性能.
主要方法:
- 使用ZnCl2激活的香假体活性炭 (BPAC) 合成.
- 针对激活温度,浸比率和热解时间的CCRD优化.
- 使用BET,XRD和零电荷点的确定进行表征.
- 根据伪二次动力学和兰格穆尔异热模型进行批量吸附研究.
主要成果:
- 实现了2415m2g-1的特定表面积,超过了预测的1037m2g-1.1.
- 确定了最佳条件:400°C的激活温度,2:1的浸比率,1小时的热解时间.
- 在7小时内达到酸盐吸附平衡.
- 根据Langmuir模型确定的最大吸附能力为11.78毫克g-1.
- 在零电荷点 (7.30) 的pH值表明吸附在此值以下.
结论:
- 香伪体是高表面积活性炭的可行前体.
- 热解后的清洁对表面积产生了重大影响.
- 开发的BPAC显示了从水溶液中有效去除酸盐的有希望的潜力.
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