双层涂层磁铁纳米颗粒作为磁性吸附剂,以有效地去除paraquat
Senee Kruanetr1, Ratchaneekorn Pilasombat1, Widchaya Radchatawedchakoon1
1Creative Chemistry and Innovation Research Unit, Center of Excellence for Innovation in Chemistry (PERCH-CIC), Department of Chemistry, Faculty of Science, Mahasarakham University, Mahasarakham 44150, Thailand.
涂有脂肪酸的磁铁纳米颗粒有效地从水中去除有毒除草剂帕拉克瓦特. 这些可重复使用,磁性可回收的纳米吸收剂为水处理提供了具有成本效益的解决方案.
科学领域:
- 环境科学 环境科学
- 材料科学 材料科学 材料科学
- 纳米技术 纳米技术
背景情况:
- 帕拉奎特 (PQ2+) 由于其持久性和毒性,造成环境风险.
- 开发高效且可重复使用的吸附剂对于水资源整治至关重要.
研究的目的:
- 合成和评估以酸 (LA) 和棕酸 (PA) 涂层的磁石纳米颗粒 (Fe3O4@LA和Fe3O4@PA) 用于去除帕奎特.
- 研究这些新型纳米吸收剂的结构性,磁性和吸附性质.
主要方法:
- 连续流的共同沉用于合成双层涂层Fe3O4纳米粒子.
- 使用TEM,XRD,FTIR,TGA,BET和VSM进行表征.
- 批量吸附实验以确定吸附能力,动力学和热力学.
主要成果:
- Fe3O4@LA纳米颗粒的最大吸附能力 (14.8毫克g-1) 比Fe3O4@PA (11.2毫克g-1) 高.
- 吸附跟随伪二次动力学,表明化学吸收.
- 纳米吸收剂在六个周期内表现出极好的可重复使用性,容量损失最小.
结论:
- 脂肪酸双层涂层的Fe3O4纳米颗粒是有效的,磁性可回收,可重复使用的吸附剂,用于去除paraquat.
- Fe3O4@LA的增强性能归因于利诺基酸的不和结构,促进了更强的相互作用.
- 这些材料是一个有希望的,环保的方法来处理除草剂污染的水.
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