二 ((2,3,9,10,16,17,23,24-octafluorophthalocyanine):从合成到异构连接装置的过程
Petr Bečvář1, Stephane Brandès1, Lucas Vachey1
1UMR CNRS 6302, Institut de Chimie Moléculaire de l'Université de Bourgogne (ICMUB), Université Bourgogne Europe, 9 avenue Alain Savary, Dijon Cedex 21078, France.
化二甲氨酸 (Lu(F8Pc) 2) 的合成和研究. 这种新型的半导体及其与二甲氨酸 (LuPc) 的异质连接显示出对氨的相反反应,提供了新的见解.
科学领域:
- 材料科学 材料科学 材料科学
- 有机电子 有机电子
- 分子半导体分子半导体
背景情况:
- 二甲氨酸 (LuPc) 是一种已知的分子半导体.
- LuPc的化衍生物在很大程度上是未被探索的.
- 对于先进的材料来说,了解phthalocyanines中的结构性质关系至关重要.
研究的目的:
- 为了合成和描述 lutetium octafluorosubstituted bisphthalocyanine (Lu(F8Pc) 2) 的特性.
- 为了评估Lu (F) 片的电性能和氨反应.
- 为了研究Lu(F8Pc) 2和LuPc2的双层异质连接.
主要方法:
- 通过直接合成或从H2F8Pc前体中合成Lu.
- 使用质谱学和光学光谱学进行表征.
- 滴膜和双层异质连接的制造和电气评估.
主要成果:
- 成功合成和表征Lu(F8Pc) 2 .
- (F8Pc) 2电阻对氨有积极的反应.
- (F8Pc) 2/LuPc2异质连接对氨有负面反应.
结论:
- ((F8Pc) 2是一种有前途的分子半导体,具有独特的电气性能.
- 与非化类似物相比,化显著改变了氨的感知行为.
- 异质连接中的相反反应为基于氨酸的传感器提供了有价值的结构属性见解.
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