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Updated: Jan 28, 2026

Adsorption Device Based on a Langatate Crystal Microbalance for High Temperature High Pressure Gas Adsorption in Zeolite H-ZSM-5

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Published on: August 25, 2016

高温和低度深层烟气脱硫,使用低Si/Al (∼5) 比率的酸Na-SSZ-13

Xiao-Hong Xiong¹, Xiang-Qiong Jiang², Liang Song²

¹Department of Chemistry and Chemical Engineering, Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Shantou, China.

Small (Weinheim an der Bergstrasse, Germany)

|January 27, 2026

概括

我们开发了一种稳定的Na-SSZ-13热石,用于有效地从烟气中捕获和回收二氧化硫 (SO2). 这种材料表现出极好的稳定性和高的SO2吸附能力,这对于深层烟气脱硫至关重要.

科学领域:

材料科学材料科学材料科学
化学工程是化学工程的重要组成部分.
环境科学环境科学

背景情况:

深度烟气脱硫 (FGD) 和二氧化硫 (SO2) 恢复需要高度稳定的多孔材料,由于SO2的腐蚀性.
现有的多孔材料在苛刻的FGD场景中往往难以保持稳定性和效率.

研究的目的:

为了合成和评估稳定的微孔热岩,Na-SSZ-13,对SO2吸附和回收的性能.
调查SO2吸附机制,并评估其适用于在具有挑战性的条件下深度FGD的适用性.

主要方法:

合成低Si/Al比率的Na-SSZ-13地石.
系统评估动态SO2吸附性能,包括稳定性 (水,热,化学) 和选择性.
列突破实验,GCMC模拟,DFT计算和现场DRIFT分析.

主要成果:

Na-SSZ-13 具有卓越的水,热和化学稳定性.
高的SO2亲和力,吸附动力学和非凡的SO2/CO2选择性 (2673在零覆盖).
特别低度的SO2吸附能力 (4.6/2.7 mmol g-1在0.1/0.002 bar) 和高温 (323423 K) 的烟气混合物中的有效捕获.
在再生过程中达到96.5%的SO2纯度,具有出色的循环稳定性.

结论:

Na-SSZ-13是一种高度稳定且有效的材料,用于深层烟气脱硫和SO2回收.
纳+反子在通过·····················································································································································································································································································································································································································································································································································
这种以热带石为基础的材料对高温,低度的SO2捕获应用具有显著的前景.

关键词:

吸附和分离SO2的吸附和分离.这是SSZ-13.烟气深度去硫化烟气深度去硫化泽奥利特石是一种热带石.

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