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相关概念视频

Network Covalent Solids02:18

Network Covalent Solids

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Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
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Covalent Bonds01:29

Covalent Bonds

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Overview
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Covalent Bonds01:08

Covalent Bonds

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When two atoms share electrons to complete their valence shells, they create a covalent bond. An atom's electronegativity—the force with which shared electrons are pulled towards an atom—determines how the electrons are shared. Molecules formed with covalent bonds can be either polar or nonpolar. Atoms with similar electronegativities form nonpolar covalent bonds; the electrons are shared equally. Atoms with different electronegativities share electrons unequally,...
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Covalently Linked Protein Regulators02:04

Covalently Linked Protein Regulators

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Proteins can undergo many types of post-translational modifications, often in response to changes in their environment. These modifications play an important role in the function and stability of these proteins. Covalently linked molecules include functional groups, such as methyl, acetyl, and phosphate groups, and also small proteins, such as ubiquitin. There are around 200 different types of covalent regulators that have been identified.
These groups modify specific amino acids in a protein....
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Covalent Bonding and Lewis Structures02:46

Covalent Bonding and Lewis Structures

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Compared to ionic bonds, which results from the transfer of electrons between metallic and nonmetallic atoms, covalent bonds result from the mutual attraction of atoms for a “shared” pair of electrons.
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Position and Displacement01:31

Position and Displacement

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The position of an object defines its location relative to a convenient frame of reference at any particular time. A frame of reference is an arbitrary set of axes from which the position and motion of an object are described. Earth is often used as a frame of reference, and we often describe the position of an object as it relates to stationary objects on Earth. For example, a rocket launch could be described in terms of the position of the rocket with respect to Earth as a whole. On the other...
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相关实验视频

Updated: Jan 28, 2026

Microfluidic-based Synthesis of Covalent Organic Frameworks COFs: A Tool for Continuous Production of COF Fibers and Direct Printing on a Surface
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Microfluidic-based Synthesis of Covalent Organic Frameworks COFs: A Tool for Continuous Production of COF Fibers and Direct Printing on a Surface

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在二维共价有机框架中通过间层静电排斥实现旋转堆叠位移.

Xinkun Ma1, Wang-Kang Han1, Haishan Zhu2

  • 1School of Chemistry, Chemical Engineering and Biotechnology, Nanyang Technological University, Singapore, Singapore.

Angewandte Chemie (International ed. in English)
|January 27, 2026
PubMed
概括

研究人员开发了一种新方法,通过调整静电排斥来控制2D共价有机框架 (2D COF) 中的堆叠. 这允许多样化,可调节的结构,具有改进的光电子和光催化性能.

关键词:
共价有机框架是共价有机框架.过氧化生产生产两层之间的静电排斥.光催化作用的光催化作用旋转堆叠的堆叠方式

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科学领域:

  • 材料科学 材料科学 材料科学
  • 超分子化学 超分子化学
  • 纳米技术 纳米技术

背景情况:

  • 在二维共价有机框架 (2D COF) 中调节层间堆叠对于独特的结构和光电子特性至关重要.
  • 目前的2D COF堆叠模式仅限于被遮蔽的,状的和移动的配置.

研究的目的:

  • 开发一种新的方法,以旋转堆叠构建2D COF.
  • 探索层间静电排斥的调制,以控制堆叠模式.
  • 为了增强二维COF的光电子和光催化性能.

主要方法:

  • 合成了2D COFs,使用三胺和二甲基单体与不同替代剂.
  • 研究了替代剂对层间静电排斥和堆叠模式的影响.
  • 评估了合成的COFs的光催化过氧化生产效率.

主要成果:

  • 通过调节层间静电排斥,在2D COF中实现了旋转和阴影 (AA) 堆叠.
  • 证明替代剂可以改变堆叠模式并将无形材料转化为晶体材料.
  • 展示了多组件堆叠调节策略可以增强光催化过氧化的产生.

结论:

  • 利用层间排斥提供了一个强大的策略,以定制二维COF中的层间堆叠.
  • 这种方法使二维COF拓多样化,并大大提高了它们的光电子特性.
  • 这些发现为设计各种应用的先进2D COF 开辟了新的途径.