在冷却过程和机制下将三酸晶体形式转化为钢,以增强水化活性
Xi Zhang1,2, Jiale He1, Chunhui Gu1
1College of Metallurgy and Energy, North China University of Science and Technology, 21 Bohai Avenue, Tangshan, 063210, P.R. China. wangyj@ncst.edu.cn.
Analytical methods : advancing methods and applications
|January 27, 2026
概括
优化钢冷却将低活性T1-C3S转化为高活性M3-C3S. 这一过程减少了污染,并增强了钢.
科学领域:
- 材料科学 材料科学 材料科学
- 环境工程 环境工程
- 金工程 金工程 金工程
背景情况:
- 钢是一种散装固体废物,带来了土地占用和污染等环境风险.
- 钢中的低活性T1-C3S相具有有限的工业应用.
- 转化钢对于可持续的金工艺和废物利用至关重要.
研究的目的:
- 通过优化冷却,实现T1-C3S-to-M3-C3S转化为钢.
- 研究冷却诱导的相变的机制及其对钢铁渣性能的影响.
- 支持钢的高价值利用,并促进绿色金实践.
主要方法:
- 优化钢合成的冷却参数.
- 准备和表征纯相C3S多态.
- 使用第一原则计算来探索结构-反应性关系.
- 分析快速冷却对钢颗粒形态和孔隙结构的影响.
主要成果:
- 增加的冷却速率会削弱纯相C3S的晶格幅度.
- 在合成温度下冷却水有利于更高的T1-C3S质量分数.
- MgO固体溶液促进了T1-C3S到M3-C3S的转化,最大限度地提高了M3-C3S的含量.
- 快速冷却增强了钢颗粒的裂变,增加了孔隙性,并改善了与建筑材料的兼容性.
结论:
- 优化的冷却过程使T1-C3S-to-M3-C3S转化为钢.
- 这种转化减轻了固体废物的二次污染,并提高了材料的性能.
- 该研究为高价值利用钢和更绿色的金工艺提供了基础.
相关概念视频
Mechanical Characteristics of Steel
1.1K
The mechanical characteristics of steel are assessed through various tests that evaluate its strength, toughness, and flexibility. These tests include tension, torsion, impact, bending, and hardness assessments, each providing crucial information about steel's suitability for specific applications.
The tension test is fundamental for determining tensile strength. In this test, a steel specimen is stretched using a gripping device until it breaks. The data collected during this test are used...
The tension test is fundamental for determining tensile strength. In this test, a steel specimen is stretched using a gripping device until it breaks. The data collected during this test are used...
1.1K
Heating and Cooling Curves
27.6K
When a substance—isolated from its environment—is subjected to heat changes, corresponding changes in temperature and phase of the substance is observed; this is graphically represented by heating and cooling curves.
For instance, the addition of heat raises the temperature of a solid; the amount of heat absorbed depends on the heat capacity of the solid (q = mcsolidΔT). According to thermochemistry, the relation between the amount of heat absorbed or released by a substance, q, and its...
For instance, the addition of heat raises the temperature of a solid; the amount of heat absorbed depends on the heat capacity of the solid (q = mcsolidΔT). According to thermochemistry, the relation between the amount of heat absorbed or released by a substance, q, and its...
27.6K
Aqueous Solutions and Heats of Hydration
17.9K
Water and other polar molecules are attracted to ions. The electrostatic attraction between an ion and a molecule with a dipole is called an ion-dipole attraction. These attractions play an important role in the dissolution of ionic compounds in water.
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...
17.9K
Hydration of Cement
896
Hydration of cement is a chemical reaction between cement particles and water. This process occurs primarily through two mechanisms: through-solution and topochemical. In the through-solution process, anhydrous compounds dissolve into their constituents, hydrates form in the solution, and then precipitate from the supersaturated solution. The topochemical process involves solid-state reactions at the cement particle surface. The through-solution process dominates the topochemical process at the...
896
Reaction Mechanisms
30.7K
Chemical reactions often occur in a stepwise fashion, involving two or more distinct reactions taking place in a sequence. A balanced equation indicates the reacting species and the product species, but it reveals no details about how the reaction occurs at the molecular level. The reaction mechanism (or reaction path) provides details regarding the precise, step-by-step process by which a reaction occurs.
For instance, the decomposition of ozone appears to follow a mechanism with two steps:
For instance, the decomposition of ozone appears to follow a mechanism with two steps:
30.7K
Steel Fastening Techniques
1.3K
Steel sections can be joined together through various fastening techniques including riveting, bolting, and welding, each suitable for different structural requirements and conditions.
Rivets are cylindrical steel fasteners with a specially designed head. During application, rivets are heated until white-hot and then inserted through pre-drilled holes in the steel sections. A pneumatic hammer is used to shape the exposed end into a second head, securing the sections together.
Bolting is another...
Rivets are cylindrical steel fasteners with a specially designed head. During application, rivets are heated until white-hot and then inserted through pre-drilled holes in the steel sections. A pneumatic hammer is used to shape the exposed end into a second head, securing the sections together.
Bolting is another...
1.3K


