近红外光子金属有机框架
He-Qi Zheng1, Qi Zhang1, Yuanjing Cui1
1State Key Laboratory of Silicon and Advanced Semiconductor Materials, ZJU-Hangzhou Global Scientific and Technological Innovation Center, School of Materials Science & Engineering, Zhejiang University, Hangzhou 310027, China.
金属有机框架 (MOF) 是为近红外 (NIR) 光子应用而设计的,利用它们的多孔结构来增强先进技术的光发射和吸收.
科学领域:
- 材料科学 材料科学 材料科学
- 光子学是指光子学的使用方法.
- 纳米技术 纳米技术
背景情况:
- 近红外 (NIR) 光,特别是NIR-II (1000-2000nm),提供了诸如深层组织透和低光学损失等优势.
- 金属有机框架 (MOF) 是晶体多孔材料,具有可调节的结构和永久的多孔性,这使得它们对光子应用具有前景.
研究的目的:
- 总结最近在设计和建造NIR光子MOF方面的进展.
- 突出这些MOFs独特的NIR光子特性和多样化的应用.
主要方法:
- 将NIR响应的无机和有机单元纳入MOF结构.
- 在MOF毛孔内封装NIR反应的光子物种 (例如,兰化离子,染料,纳米粒子).
- 混合兰化物MOF,多变体联体MOF,染料封装MOF以及纳米粒子/MOF复合材料的设计.
主要成果:
- 展示关键的NIR光子功能,包括NIR光发光,多光子发光,激光,波频率生成和非线性光学行为.
- 在发光温度传感,3D图案,光子数据存储,微纳米激光和生物成像中成功应用NIR光子MOF.
结论:
- NIR光子MOF为开发先进的光子材料提供了一个多功能平台.
- 对MOF设计和合成的进一步研究可以释放新的NIR光子特性,并扩展其在传感,激光,数据存储和生物医学中的应用.
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