提高碳素终结聚乙烯 (CTPB) 结合剂系统的机械性能,使用固化加速器
Xiao Qu1, Peixuan Hu1,2, Xinyi Ma1
1School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China.
Molecules (Basel, Switzerland)
|January 28, 2026
概括
这项研究引入了一种新型治愈加速器,以增强固体推进剂的氧树脂 (EP) 结合系统. 优化的系统显示了显著改善的机械性能和更快的固化速率.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 推进剂技术 推进剂技术 推进剂技术
背景情况:
- 碳素终结聚乙烯 (CTPB) /环氧树脂 (EP) 粘合剂系统对于固体推进剂至关重要,但患有缓慢固化,后固化问题和不充分的机械性能.
- 优化固化过程对于提高固体推进剂应用中的粘合剂性能和可靠性至关重要.
研究的目的:
- 通过引入一种新的固化加速器来优化固体推进剂的CTPB/EP粘合剂系统.
- 研究固化加速器对粘合剂系统固化动力学和机械性能的影响.
- 建立基于CTPB的粘合剂系统的准备方法,以增强延伸和拉伸强度.
主要方法:
- 在CTPB/EP结合剂系统中将593个异形氨基化合物作为治愈加速器进行了整合.
- 评估机械性能,包括断裂强度和断裂时的延伸.
- 确定交联密度,凝分数和固化反应的激活能量.
主要成果:
- 添加愈合加速器显著改善了CTPB/EP粘合剂系统的断裂强度和断裂时的延长.
- 使用0.3%重量%的固化加速器,拉力断裂强度达到0.37 MPa,断裂时的延长达到655%.
- 增加的固化加速器含量显著提高了交联密度 (4.3 × 10-4 mol/cm 在0.3 wt.%) 和降低了激活能量,表明更快的固化.
结论:
- 开发的CTPB/EP粘合器系统具有很高的延伸和抗拉强度,解决了传统系统的局限性.
- 该研究为在固体推进剂配方中使用具有增强性能的CTPB型粘合剂系统提供了坚实的科学基础.
- 这些发现为通过优化粘合剂化学改善固体推进剂性能和可靠性铺平了道路.
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