工艺控制的功能性聚合物薄膜在纸上:PVA-氨酸涂层的氧障碍和抗菌性能
Korakot Charoensri1, Dae Hyeon Kwon2,3, Hong Seok Kim3
1Department of Imaging and Printing Technology, Faculty of Science, Chulalongkorn University, Bangkok 10330, Thailand.
Polymers
|January 28, 2026
概括
在纸上实现连续的聚合物薄膜需要超过5微米厚的多层涂层,以获得最佳的氧气屏障性能. 这些功能性涂料还为可持续包装提供抗菌性质.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 纳米技术 纳米技术
背景情况:
- 多孔纸质基板对连续的功能性聚合物薄膜形成构成挑战,影响屏障特性.
- 基板引起的缺陷,如针孔,阻碍了薄膜连续性和单层涂料的性能.
研究的目的:
- 研究用纸上ZnO纳米颗粒涂层的粉-聚乙烯醇 (PVA) 的工艺结构-性能关系.
- 确定关键薄膜厚度,以实现有效的氧气屏障性能.
- 评估涂料的耐湿性,抗菌活性和可持续性方面.
主要方法:
- 通过水性沉积制造含有ZnO纳米颗粒的粉素-PVA涂层.
- 系统的多层沉积,以克服基质诱导的缺陷.
- 评估氧气传递率,耐湿性,抗微生物活性,机械灵活性和反性.
主要成果:
- 单层涂层由于缺陷而出现严重的屏障故障.
- 多层沉积使连续薄膜成为可能,氧气传递率在大约5μm厚度之外显著下降.
- 带有 ZnO NP 的涂层表现出对大肠杆菌和金黄色葡萄球菌的广泛抗菌活性.
- 涂料表现出足够的机械灵活性和高反弹性.
结论:
- 大约5μm的临界干层厚度对于在纸上设计高性能氧气屏障至关重要.
- 开发的涂层为积极和可持续的基于纸的包装提供了多功能潜力.
- 定量关键薄膜厚度为多孔基板上的功能聚合物涂层提供了设计指南.
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