离子银和银纳米颗粒的差异毒性:生态毒理学研究的元分析
Esra Karaman1, Deniz Boz Eravci2, Selim Latif Sanin1
1Department of Environmental Engineering, Institute of Science, Hacettepe University, 06800 Ankara, Türkiye.
Toxics
|January 28, 2026
概括
银酸盐 (AgNO3) 在各种物种中通常比银纳米粒子 (AgNPs) 更有毒. 毒性随着暴露时间的变化而显著变化,这突显出需要对不同形式的白银进行细致的环境风险评估.
科学领域:
- 环境科学 环境科学
- 生态毒理学 生态毒理学
- 化学 化学 化学
背景情况:
- 近年来,人们越来越多地研究银金属的毒性.
- 现有的研究在银形式,试验生物和暴露时间方面存在差异,这阻碍了比较分析和指导方针的制定.
研究的目的:
- 进行系统的分析,比较银酸盐 (AgNO3) 和银纳米粒子 (AgNPs) 的毒性.
- 为了澄清广泛的生物多样性物种的比较毒性.
- 确定影响银毒性的关键因素,包括形式,剂量,暴露时间和生物体类型.
主要方法:
- 1945年至2024年间发表的1117项研究的系统选.
- 分析了来自11项符合资格研究的28个数据集,这些数据集符合质量标准.
- 对银的毒性进行量化数据的综合分析.
主要成果:
- 在大多数情况下,银酸盐 (AgNO3) 的毒性比银纳米粒子 (AgNPs) 高.
- 暴露时间显著影响了毒性,短期 (≥3小时) 和长期 (≥96小时) 暴露之间存在显著差异.
- 银的毒性取决于银的形式,暴露剂量,持续时间和生物体类型.
结论:
- 银的毒性取决于形状,AgNO3通常比AgNPs更有毒.
- 暴露时间是决定银的生态毒理作用的关键因素.
- 这一元分析为改善银形式的环境风险评估提供了定量综合.
相关概念视频
Solubility of Ionic Compounds
68.1K
Solubility is the measure of the maximum amount of solute that can be dissolved in a given quantity of solvent at a given temperature and pressure. Solubility is usually measured in molarity (M) or moles per liter (mol/L). A compound is termed soluble if it dissolves in water.
68.1K
Ionic Radii
33.5K
Ionic radius is the measure used to describe the size of an ion. A cation always has fewer electrons and the same number of protons as the parent atom; it is smaller than the atom from which it is derived. For example, the covalent radius of an aluminum atom (1s22s22p63s23p1) is 118 pm, whereas the ionic radius of an Al3+ (1s22s22p6) is 68 pm. As electrons are removed from the outer valence shell, the remaining core electrons occupying smaller shells experience a greater effective nuclear...
33.5K
Ionic Bonds
130.3K
Overview
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
130.3K
Molecular and Ionic Solids
20.0K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
20.0K
Ionic Crystal Structures
17.0K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
17.0K
Ionic Compounds: Formulas and Nomenclature
86.9K
An element composed of atoms that readily lose electrons (a metal) can react with an element composed of atoms that readily gain electrons (a nonmetal) to produce ions through complete electron transfer. The compound formed by this transfer is stabilized by the electrostatic attractions (ionic bonds) between the oppositely charged ions.
86.9K


